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Solid-state structure of compound 4 with ellipsoids at 30% of probability. Hydrogen atoms, except those of the benzene ring, are omitted for clarity. Selected average bond distances (Å) and angles (°): Ti–N 2.014(4), Ti–C 2.23(5), C–C 1.451(4), Ti-centroid 1.691(3), N–Ti–N 78.63(6).
