Table 5. Parameters of the λh Model and the Polynomial Empirical Model (P = 101.3 kPa)^a,^b.

	λh model			polynomial empirical model
solvents	100R2	λ	h	100R2	A3	B3	C3	D3
acetonitrile	99.60	0.08 ± 5.88 × 10–3	15759.56 ± 601.45	99.92	–2.78 ± 0.73	0.03 ± 7.20 × 10–3	–9.46 × 10–5 ± 2.38 × 10–5	1.07 × 10–7 ± 2.61 × 10–8
DMF	99.93	0.93 ± 0.05	4130.14 ± 182.22	99.98	–2.04 ± 0.30	0.02 ± 2.94 × 10–3	–7.35 × 10–5 ± 9.70 × 10–6	8.57 × 10–8 ± 1.07 × 10–8
acetone	99.68	0.13 ± 0.01	25325.73 ± 1859.73	99.75	0*	0*	0*	0*
2-butanone	99.97	0.46 ± 0.01	7268.96 ± 162.94	99.97	0*	2.42 × 10–3 ± 2.72 × 10–3	–1.05 × 10–5 ± 8.99 × 10–6	1.51 × 10–8 ± 9.89 × 10–9
4-methyl-2-pentanone	98.97	0.02 ± 3.07 × 10–3	61218.96 ± 4271.03	99.39	–1.14 ± 0.47	0.01 ± 4.63 × 10–3	–3.82 × 10–5 ± 1.53 × 10–5	4.27 × 10–8 ± 1.68 × 10–8
ethyl formate	99.69	0.20 ± 0.02	17198.95 ± 1367.28	99.87	0*	2.41 × 10–3 ± 2.41 × 10–3	–9.27 × 10–6 ± 7.97 × 10–6	1.19 × 10–8 ± 8.77 × 10–9
methyl acetate	99.35	0.14 ± 0.02	19040.70 ± 1617.46	99.49	1.02 ± 0.79	–9.95 × 10–3 ± 7.88 × 10–3	3.21 × 10–5 ± 2.60 × 10–5	–3.40 × 10–8 ± 2.8610–8
ethyl acetate	99.76	0.03 ± 1.57 × 10–3	65461.72 ± 2368.57	99.74	0*	0*	0*	0*
propyl acetate	99.28	0.08 ± 0.01	34341.12 ± 3247.92	99.94	0.20 ± 0.13	–1.71 × 10–3 ± 1.31 × 10–3	0*	0*
butyl acetate	99.80	0.11 ± 9.14 × 10–3	33568.65 ± 2257.24	99.90	0*	7.82 × 10–4 ± 1.03 × 10–3	0*	3.83 × 10–9 ± 3.76 × 10–9
methyl propionate	99.53	0.03 ± 2.22 × 10–3	60923.82 ± 2964.81	99.67	0*	0*	0*	0*
ethanol	99.80	0.08 ± 8.53 × 10–3	56639.38 ± 5003.79	99.77	0*	0*	0*	1.80 × 10–9 ± 1.59 × 10–9
1-propanol	99.65	0.20 ± 0.04	28025.26 ± 4390.36	99.69	–0.12 ± 0.04	1.25 × 10–3 ± 3.95 × 10–4	–4.34 × 10–6 ± 1.30 × 10–6	5.03 × 10–9 ± 1.43 × 10–9

^aStandard uncertainty u(P) = 0.3 kPa.

^b0* indicates that the parameter has no significance and is not statistically significant.