Table 7. Thermodynamic Parameters of the Dissolution Process of EP in 13 Pure Solvents (P = 101.3 kPa)a.
| solvents | 100R2 | intercept | slope | ΔsolS° (J/(mol·K)) | ΔsolH° (kJ/mol) | ΔsolG° (kJ/mol) | ξH/% | ξTS/% |
|---|---|---|---|---|---|---|---|---|
| acetonitrile | 99.52 | –3.95 ± 5.02 × 10–3 | –1454.32 ± 35.55 | 7.06 | 12.09 | 9.95 | 84.96 | 15.04 |
| DMF | 99.87 | –5.14 ± 6.73 × 10–3 | –3804.11 ± 47.68 | 61.58 | 31.63 | 12.96 | 62.88 | 37.12 |
| acetone | 99.21 | –6.27 ± 0.01 | –3142.01 ± 98.82 | 34.02 | 26.12 | 15.81 | 71.69 | 28.31 |
| 2-butanone | 99.96 | –5.21 ± 3.25 × 10–3 | –3354.22 ± 23.02 | 48.71 | 27.89 | 13.12 | 65.38 | 34.62 |
| 4-methyl-2-pentanone | 99.06 | –5.56 ± 8.38 × 10–3 | –1719.20 ± 59.33 | 0.96 | 14.29 | 14.00 | 98.01 | 1.99 |
| ethyl formate | 99.44 | –6.15 ± 0.01 | –3319.20 ± 87.94 | 39.89 | 27.60 | 15.50 | 69.53 | 30.47 |
| methyl acetate | 99.61 | –5.38 ± 8.45 × 10–3 | –2704.92 ± 59.83 | 29.46 | 22.49 | 13.56 | 71.58 | 28.42 |
| ethyl acetate | 99.61 | –5.77 ± 5.82 × 10–3 | –1857.99 ± 41.20 | 2.97 | 15.45 | 14.55 | 94.49 | 5.51 |
| propyl acetate | 98.54 | –6.15 ± 0.02 | –2667.20 ± 114.76 | 22.05 | 22.18 | 15.49 | 76.84 | 23.16 |
| butyl acetate | 99.73 | –6.94 ± 9.66 × 10–3 | –3704.77 ± 68.41 | 43.94 | 30.80 | 17.48 | 69.81 | 30.19 |
| methyl propionate | 99.36 | –5.64 ± 7.16 × 10–3 | –1783.94 ± 50.75 | 2.05 | 14.83 | 14.21 | 95.98 | 4.02 |
| ethanol | 99.72 | –8.47 ± 0.01 | –4556.31 ± 85.20 | 54.56 | 37.88 | 21.34 | 69.61 | 30.39 |
| 1-propanol | 99.66 | –8.95 ± 0.02 | –5320.97 ± 109.63 | 71.49 | 44.24 | 22.57 | 67.12 | 32.88 |
Standard uncertainty u(P) = 0.3 kPa.