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. 2024 May 2;9(19):21333–21345. doi: 10.1021/acsomega.4c01550

Table 7. Thermodynamic Parameters of the Dissolution Process of EP in 13 Pure Solvents (P = 101.3 kPa)a.

solvents 100R2 intercept slope Δsol (J/(mol·K)) Δsol (kJ/mol) Δsol (kJ/mol) ξH/% ξTS/%
acetonitrile 99.52 –3.95 ± 5.02 × 10–3 –1454.32 ± 35.55 7.06 12.09 9.95 84.96 15.04
DMF 99.87 –5.14 ± 6.73 × 10–3 –3804.11 ± 47.68 61.58 31.63 12.96 62.88 37.12
acetone 99.21 –6.27 ± 0.01 –3142.01 ± 98.82 34.02 26.12 15.81 71.69 28.31
2-butanone 99.96 –5.21 ± 3.25 × 10–3 –3354.22 ± 23.02 48.71 27.89 13.12 65.38 34.62
4-methyl-2-pentanone 99.06 –5.56 ± 8.38 × 10–3 –1719.20 ± 59.33 0.96 14.29 14.00 98.01 1.99
ethyl formate 99.44 –6.15 ± 0.01 –3319.20 ± 87.94 39.89 27.60 15.50 69.53 30.47
methyl acetate 99.61 –5.38 ± 8.45 × 10–3 –2704.92 ± 59.83 29.46 22.49 13.56 71.58 28.42
ethyl acetate 99.61 –5.77 ± 5.82 × 10–3 –1857.99 ± 41.20 2.97 15.45 14.55 94.49 5.51
propyl acetate 98.54 –6.15 ± 0.02 –2667.20 ± 114.76 22.05 22.18 15.49 76.84 23.16
butyl acetate 99.73 –6.94 ± 9.66 × 10–3 –3704.77 ± 68.41 43.94 30.80 17.48 69.81 30.19
methyl propionate 99.36 –5.64 ± 7.16 × 10–3 –1783.94 ± 50.75 2.05 14.83 14.21 95.98 4.02
ethanol 99.72 –8.47 ± 0.01 –4556.31 ± 85.20 54.56 37.88 21.34 69.61 30.39
1-propanol 99.66 –8.95 ± 0.02 –5320.97 ± 109.63 71.49 44.24 22.57 67.12 32.88
a

Standard uncertainty u(P) = 0.3 kPa.