Table 4. Changes in the Vibrational Term Values (ΔGnav, in Inverse Centimeters) for the X2Σ+ State of 24MgH Calculated Taking into Account the Nonadiabatic Effects.
| v | VRMa | TSOb | ARMc |
|---|---|---|---|
| 0 | –0.25 | –0.22 | –0.20 |
| 1 | –0.72 | –0.63 | –0.56 |
| 2 | –1.19 | –1.03 | –0.89 |
| 3 | –1.64 | –1.43 | –1.18 |
| 4 | –2.10 | –1.84 | –1.43 |
| 5 | –2.56 | –2.26 | –1.62 |
| 6 | –2.98 | –2.66 | –1.74 |
| 7 | –3.30 | –2.97 | –1.76 |
| 8 | –3.37 | –3.06 | –1.62 |
| 9 | –2.83 | –2.60 | –1.25 |
| 10 | –1.32 | –1.23 | –0.57 |
| 11 | –0.29 | –0.27 | –0.13 |
Predicted using the effective vibrational reduced mass μv = μ/(1 + β).
Predicted using the parameter β modified to account only for the interaction between two states X2Σ+ and B′2Σ+; see the text.
Predicted using the atomic reduced mass μat.