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Isothermal, pulsed MB measurements on Au(111) (black) and Au(332) (red) at 230 K with a continuous methanol supply and a pulsed flux of atomic oxygen. (a) MeFo formation rate measured by mass spectrometry (m/z = 60). (b) Formate accumulation given as an (integrated) νs(OCO)-IRAS-intensity around 1330 cm–1.
