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. 2024 May 8;15(20):7474–7501. doi: 10.1039/d4sc01793e

Fig. 12. (A) Temperature evolution of the distribution of the total pore volume, determined for a standard probe of radius 1.2 Å. The average pore volume takes the following values: 52 cm3 kg−1 at 27 °C, 49 cm3 kg−1 at 1727 °C, and 41 cm3 kg−1 at 1977 °C. (B) Atomic configuration of the ZIF melt, gained from reverse Monte Carlo modeling of the total scattering data collected at 583 °C. Free volume is represented in orange, Zn atoms in green, N in blue, and C in grey. Adapted with permission from ref. 29. Copyright 2017 Springer Nature Limited.

Fig. 12