Fig. 12. (A) Temperature evolution of the distribution of the total pore volume, determined for a standard probe of radius 1.2 Å. The average pore volume takes the following values: 52 cm3 kg−1 at 27 °C, 49 cm3 kg−1 at 1727 °C, and 41 cm3 kg−1 at 1977 °C. (B) Atomic configuration of the ZIF melt, gained from reverse Monte Carlo modeling of the total scattering data collected at 583 °C. Free volume is represented in orange, Zn atoms in green, N in blue, and C in grey. Adapted with permission from ref. 29. Copyright 2017 Springer Nature Limited.
