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. 2024 May 8;15(20):7474–7501. doi: 10.1039/d4sc01793e

Fig. 8. Modification of melting behavior and properties of melts through the addition of network modifiers. (A) Schematic diagram depicting the process of soda-lime silica glass formation by introducing network modifiers like Na2O and CaO, accompanied by their corresponding temperature-dependent viscosity profiles. (B) Approximate relation between molecular weight, glass transition temperature (Tg, blue line), melting point (Tm, red line), and polymer properties.117 (C) A diagram demonstrating composition-dependent solidus and liquidus points of the CsHSO4–ZnPIm binary system at ambient pressure. Blue hexagons and red circles represent the invariant point and temperature of the liquidus, respectively. The diagram has three regions: mixed solids (blue), incongruent melting (purple), and liquid phase (red). (D) Temperature-dependent viscosity of CsHSO4, ZnPIm-g, and [CsHSO4]0.5[ZnPIm]0.5-g over heating scan. (E) Simulated average coordination number of the Co–O correlation in Co(hmba)3[CoBr4] structures containing 0, 1, 2, or 3 water molecules. (B and C) are adapted with permission from ref. 107. Copyright 2022 American Chemical Society. (D) is adapted with permission from ref. 118. Copyright 2023 John Wiley & Sons, Inc. under Creative Commons license CC BY 4.0. https://creativecommons.org/licenses/by/4.0/.

Fig. 8