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. 2024 May 10;11:1403541. doi: 10.3389/fnut.2024.1403541

Table 3.

List of quantifier and qualifier ions (m/z) used in GC–MS/MS method for PAHs, PAHs-d12, and PCB-209 determination.

Analyte RTa Quantifier ion Transition CEb Qualifier ion Transition CEb
BAP 16.97 252 252 → 250 45 252 252 → 224 60
BAP-d12 16.92 264 264.1 → 260.1 40 265.1 265.1 → 261.1 40
BAA 13.93 228 228 → 226 40 228 228 → 227 25
BAA-d12 13.88 240 240 → 236 40 240 240 → 238 30
BBF 16.33 252 252 → 248 60 252 252 → 224 60
BBF-d12 16.28 264.1 264.1 → 260.1 40 265.1 265.1 → 261.1 40
CHR 14.02 228 228 → 226 40 228 228 → 227 25
CHR-d12 13.96 240 240 → 238 20 240 240 → 236 38
PCB 209 17.08 497.7 497.7 → 427.7 30 495.8 495.8 → 425.7 30
a

RT Retention time (min).

b

CE collision energy (V).