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(a) Overview of the transient optical absorption data of Cr(CO)6 in octane solution following photoexcitation with a 266 nm laser pulse. (b) Transient absorption spectra for selected pump–probe delays displaying an initial broad absorption feature throughout the observed spectral range followed by formation of a transient absorption band centered at around 500 nm. The steady-state absorption spectrum of Cr(CO)6 is shown in the inset.
