Table 13.
Comparison with catalytic systems in current literatures about oxidation of cyclohexane with O2.
| Entry | Reaction Conditions | Quantitative Methods |
Conversion (%) | Selectivity a
(%) |
Reference and Year |
|---|---|---|---|---|---|
| 1 | Atomically-dispersed Co on graphitic carbon nitrogen as catalyst, solvent-free, 130 °C, 0.80 MPa O2, 6.0 h | GC + Chemical titration | 9.1 | 62 | [6] 2023 |
| 2 | Co8LaOx/WO3 Z-scheme nanocomposites as catalyst, visible light, solvent-free, 120 °C, 1.50 MPa O2, 3.0 h | GC + Chemical titration | 10.4 | 81 | [20] 2023 |
| 3 | CeMn0.5Co0.5Ox composite oxide as catalyst, solvent-free, 150 °C, 0.50 MPa O2, 2.0 h | GC + Chemical titration | 4.6 | 93 | [66] 2023 |
| 4 | Ionic liquid modified defective Co3V2O8 as catalyst, solvent-free, 150 °C, 1.00 MPa O2, 2.0 h | GC + Derivatization GC | 12.7 | 93 | [67] 2023 |
| 5 | BaCO3-CeO2 composite as catalyst, solvent-free, 150 °C, 1.00 MPa O2, 2.0 h | GC + Derivatization GC | 10.5 | 85 | [10] 2023 |
| 6 | Dimetallic MOF PCN-224(Co&Cu) as catalyst, solvent-free, 130 °C, 1.00 MPa O2, 4.0 h | GC + HPLC | 5.7 | 88 | [14] 2023 |
| 7 | Z-scheme WO3-Co3O4 as catalyst, 300 W Xe light, acetone as solvent, 120 °C, 1.50 MPa air, 8.0 h | GC | 11.5 | 99 | [75] 2023 |
| 8 | Graphene supported CoO as catalyst, NHPI as co-catalyst, acetone as solvent, 120 °C, 0.40 MPa O2, 6.0 h | GC | 32.4 | 75 | [76] 2022 |
| 9 | Co-Ti-Y trimetals on APO-5 as catalyst, BuOOH as co-catalyst, 120 °C, 3.00 MPa O2, 5.0 h | GC-MS | 41.7 | 65 | [77] 2022 |
| 10 | Dimetallic MOF Co-TCPPCu as catalyst, solvent-free, 120 °C, 1.00 MPa O2, 8.0 h | GC + HPLC | 5.3 | 95 | [15] 2022 |
| 11 | Dimetallic MOF PCN-224(Co&Ni) as catalyst, solvent-free, 130 °C, 0.80 MPa O2, 8.0 h | GC + HPLC | 7.3 | 85 | [9] 2022 |
| 12 | Mesoporous Co3O4-CeO2 as catalyst, solvent-free, 150 °C, 0.60 MPa O2, 1.5 h | GC + Chemical titration | 5.8 | 90 | [78] 2022 |
| 13 | Ce-Fe oxides derived from Prussian blue analogues as catalyst, solvent-free, 150 °C, 1.00 MPa O2, 3.0 h | GC + Derivatization GC | 9.3 | 75 | [21] 2022 |
| 14 | CoCl2 in ionic liquid nanoreactor as catalyst, solvent-free, 130 °C, 1.50 MPa O2, 1.0 h | GC + Derivatization GC | 7.8 | 74 | [7] 2022 |
| 15 | MoO3-x-Ag20Pd20 as catalyst, 300 W Xe light, acetone as solvent, 120 °C, 1.50 MPa air, 8.0 h | GC | 11.3 | 99 | [12] 2022 |
| 16 | Cu-containing beta zeolite as catalyst, solvent-free, 140 °C, 1.00 MPa O2, 2.0 h | GC | 9.7 | 94 | [79] 2022 |
| 17 | T(4-COOCH3)PPCo&Zn(AcO)2 as catalyst, solvent-free, 120 °C, 1.00 MPa O2, 8.0 h | GC + HPLC | 6.5 | 96 | [26] 2021 |
| 18 | Co3O4 in nitrogen-carbon as catalyst, acetonitrile as solvent, 110 °C, 1.00 MPa O2, 6.0 h | GC | 16.5 | 91 | [80] 2021 |
| 19 | Cerium ammonium nitrate, NHPI as catalysts, dichloroethane as solvent, 45 °C, 0.10 MPa O2, 24.0 h | GC | 9.0 | 79 | [81] 2021 |
| 20 | Pd-Ni supported on KIT-6 as catalyst, acetonitrile as solvent, 140 °C, 1.00 MPa O2, 8.0 h | GC | 10.8 | 95 | [82] 2021 |
| 21 | Co on nitrogen doped graphene as catalyst, solvent-free, 155 °C, 0.80 MPa O2, 1.5 h | GC + Chemical titration | 8.9 | 86 | [83] 2021 |
| 22 | Si@Porp. Co&Cu as catalyst, solvent-free, 120 °C, 1.00 MPa O2, 8.0 h | GC + HPLC | 5.3 | 92 | This work |
a Total selectivity towards cyclohexanol, cyclohexanone, and cyclohexyl hydroperoxide.