Table 2.
Surface tension data at T > Tk for different molecules.
| Family | Molecule | CMC (mM) |
γcmc (mN/m) |
Amin (Å2/molecule) |
ΔGmic (kcal/mol) |
ΔGads (kcal/mol) |
C20 (mM) |
pC20 | T (°C) |
|---|---|---|---|---|---|---|---|---|---|
| Alkyl glucosides |
C8αGlc | 15.5 ± 0.5 | 30.7 ± 0.3 | 43 ± 1.8 | −4.7 | −7.0 | 2.8 | 2.6 | 50 |
| C8βGlc | 21.2 ± 0.8 | 31.0 ± 0.15 | 38.5 ± 1.9 | −4.1 | −6.4 | 2.7 | 2.6 | 25 | |
| C8αGal | 51.7 ± 1.5 | 29.5 ± 0.2 | 45.8 ± 0.9 | −3.6 | −6.4 | 3.8 | 2.4 | 25 | |
| C8βGal | 20 ± 1 | 28.5 ± 0.5 | 46.3 ± 1.7 | −4.4 | −7.1 | 3.2 | 2.5 | 40 | |
| Alkyl uronates |
MeαGlc(C=O)OC6 | 55 ± 5 | 30.8 ± 0.8 | 39.2 ± 2.9 | −3.6 | −5.9 | 5.9 | 2.2 | 25 |
| MeαGlc(C=O)OC8 | 6 ± 0.5 | 29.2 ± 0.35 | 41 ± 1 | −4.8 | −7.3 | 0.5 | 3.3 | 25 | |
| MeαGlc(C=O)OC10 | 0.65 ± 0.5 | 28.1 ± 0.1 | 42.4 ± 2 | −5.9 | −8.6 | 0.05 | 4.3 | 25 | |
| MeαGlc(C=O)OC12 | 0.056 ± 0.004 | 28.3 ± 0.3 | 45.6 ± 5 | −7.2 | −10.1 | 0.004 | 5.4 | 25 | |
| MeβGal(C=O)OC8 | 6.9 ± 0.4 | 29.4 ± 0.36 | 42.9 ± 3.9 | −5.0 | −7.4 | 1.2 | 2.9 | 40 | |
| Acyl glycosides |
MeαGlcO(C=O)C5 | 105 ± 5 | 31 ± 0.1 | 40.1 ± 0.3 | −3.3 | −5.6 | 11.2 | 2.0 | 25 |
| MeαGlcO(C=O)C7 | 9.8 ± 0.76 | 29.5 ± 0.5 | 39 ± 2 | −4.5 | −6.9 | 1.0 | 3.0 | 25 | |
| MeαGlcO(C=O)C9 | 0.92 ± 0.08 | 27.9 ± 0.05 | 41.8 ± 0.9 | −5.8 | −8.4 | 0.08 | 4.1 | 30 | |
| MeαGlcO(C=O)C11 | 0.08 ± 0.005 | 26.7 ± 0.25 | 45.8 ± 2.8 | −7.7 | −10.4 | 0.007 | 5.1 | 50 | |
| MeβGalO(C=O)C7 | 8.5 ± 0.5 | 28.3 ± 0.35 | 42.7 ± 2.4 | −4.6 | −7.3 | 0.7 | 3.1 | 25 |