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. 2024 May 17;63(21):9953–9966. doi: 10.1021/acs.inorgchem.4c01021

Table 2. CHN Chemical Composition of Selected As-Made and O3-Treated Samples.

zeolite   T (°C)a timeb C (%) H (%) N (%)
SiO2-2E134TMI-STW as-made   0 12.66 1.99 3.69
  200 72 h 0.92 0.27 0.38
(Ge,Si)O2-10BDMI-HPM-8 as-made   0 11.82 1.80 2.76
  100 20 h 4.14 1.08 1.58
(Ge,Si)O2-10BDMI-POS as-made   0 11.22 1.71 2.62
  100 20 h 6.46 1.56 1.96
(Ge,Si)O2-1M3TMBI-HPM-14 as-made   0 11.15 1.57 2.71
  100 20 h 2.10 1.58 2.46
(Ge,Si)O2-1M2E3PrI-HPM-16 as-made   0 10.26 1.95 2.63
  100 5 min 7.29 1.89 2.40
  100 20 h 1.57 1.36 2.18
  150 50 h 0.28 0.84 0.16
(Ge,Si)O2-1M2E3PrI--SYT as-made   0 12.79 2.72 3.35
  100 6 h 9.50 2.40 3.04
  100 20 h 7.51 1.79 2.50
  100 30 h 2.15 1.30 2.94
SiO2-4BI-MFI as-made   0 7.50 1.29 3.19
  150 24 h 0.82 0.52 0.60
SiO2-EABO-ISV as-made   0 14.89 2.40 1.23
  180 84 h 3.62 0.66 0.32
SiO2-4bBnMI-beta as-made   0 17.46 2.10 3.04
  100 20 h 5.68 0.97 2.07
SiO2-8bDMI-beta as-made   0 11.80 1.97 2.78
  150 6 h 5.51 0.96 1.12
a

Temperature.

b

Time of the O3 treatment for the treated samples. Temperatures higher than 100 °C were only applied when long treatments at 100 °C did not afford significant detemplation.