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. 2024 May 14;16(21):3349–3363. doi: 10.1039/d3ay01333b

Selected reaction monitoring (SRM) mass transitions and the collision energies for diclofenac and its metabolites and the 13C internal standard.

Compound SRM transition CE (V)
DCF 296 → 250 quantifier 22
296 → 214 qualifier 30
13C6-DCF 302 → 256 quantifier 22
302 → 220 qualifier 30
Hydroxy-DCF 312 → 266 quantifier 22
312 → 230 qualifier 30
Cyclo-DCF 278 → 151 quantifier 70
278 → 214 qualifier 40
278 → 179 qualifier 60
13C6-Cyclo-DCF 284 → 157 quantifier 70
284 → 220 quantifier 40
284 → 185 quantifier 60
Aceclofenac 354 → 250 quantifier 22
354 → 214 qualifier 30