Selected reaction monitoring (SRM) mass transitions and the collision energies for diclofenac and its metabolites and the 13C internal standard.
Compound | SRM transition | CE (V) |
---|---|---|
DCF | 296 → 250 quantifier | 22 |
296 → 214 qualifier | 30 | |
13C6-DCF | 302 → 256 quantifier | 22 |
302 → 220 qualifier | 30 | |
Hydroxy-DCF | 312 → 266 quantifier | 22 |
312 → 230 qualifier | 30 | |
Cyclo-DCF | 278 → 151 quantifier | 70 |
278 → 214 qualifier | 40 | |
278 → 179 qualifier | 60 | |
13C6-Cyclo-DCF | 284 → 157 quantifier | 70 |
284 → 220 quantifier | 40 | |
284 → 185 quantifier | 60 | |
Aceclofenac | 354 → 250 quantifier | 22 |
354 → 214 qualifier | 30 |