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. Author manuscript; available in PMC: 2024 Aug 16.
Published in final edited form as: J Am Chem Soc. 2023 Aug 1;145(32):17919–17925. doi: 10.1021/jacs.3c05383

Scheme 4.

Scheme 4.

Substrate Scope with Respect to the Dimethyl Amide and 1-Bromo-2-iodoarene Coupling Partners.a,b,c

aConditions: 16 (0.15 mmol), 17 (0.10 mmol), Pd(CH3CN)4(BF4)2 (10 mol%), L1 (10 mol%), L6 (10 mol%), AgOAc (2.0 equiv), HFIP (0.5 mL), 80 °C, 48h. bPd(OAc)2, (20 mol%), L1 (20 mol%), L6 (20 mol%). cPd(CH3CN)4(BF4)2 (20 mol%), L1 (20 mol%), L6 (20 mol%).