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. Author manuscript; available in PMC: 2024 Aug 16.
Published in final edited form as: J Am Chem Soc. 2023 Aug 1;145(32):17919–17925. doi: 10.1021/jacs.3c05383

Scheme 5.

Scheme 5.

Dihaloarenes and Divergent Derivatization.a,b,c,d

aConditions: 15f (0.10 mmol), methyl 4-iodobenzoate or ethyl acrylate (0.20 mmol), Pd(OAc)2 (10 mol%), L2 (12 mol%), AgOAc (2.0 equiv), HFIP (0.5 mL), 70 or 80 °C, 24h. bYields were determined by 1H NMR analysis. cNone detected. dIsolated Yields.