Table 3. Experimental details.

Crystal data
Chemical formula	[Co(NCS)2(C6H7N)4]
M r	547.59
Crystal system, space group	Monoclinic, P21/c
Temperature (K)	200
a, b, c (Å)	19.0089 (7), 9.7403 (3), 16.7516 (6)
β (°)	113.370 (3)
V (Å3)	2847.15 (18)
Z	4
Radiation type	Mo Kα
μ (mm−1)	0.77
Crystal size (mm)	0.14 × 0.10 × 0.06
Data collection
Diffractometer	Stoe IPDS2
Absorption correction	Numerical (X-RED and X-SHAPE; Stoe, 2008 ▸)
T min, T max	0.735, 0.942
No. of measured, independent and observed [I > 2σ(I)] reflections	22646, 5557, 4740
R int	0.075
(sin θ/λ)max (Å−1)	0.617
Refinement
R[F 2 > 2σ(F 2)], wR(F 2), S	0.058, 0.164, 1.10
No. of reflections	5557
No. of parameters	321
H-atom treatment	H-atom parameters constrained
Δρmax, Δρmin (e Å−3)	0.37, −0.34

Computer programs: X-AREA (Stoe, 2008 ▸), SHELXT2014/4 (Sheldrick, 2015a ▸), SHELXL2016/6 (Sheldrick, 2015b ▸), DIAMOND (Brandenburg & Putz, 1999 ▸), XP in SHELXTL-PC (Sheldrick, 2008 ▸) and publCIF (Westrip, 2010 ▸).