13C (125 MHz) NMR data for compounds 1–4 in CDCl3 (δ in ppm).
| No. | 1 | 2 | 3 | 4 |
|---|---|---|---|---|
| 1 | 108.9, C | 109.7, C | 171.6, C | 173.1, C |
| 2 | 94.4, C | 81.0, C | 66.1, C | 66.3, C |
| 3 | 75.7, CH | 81.3, CH | 76.4, CH | 76.4, CH |
| 4 | 39.9, C | 38.7, C | 44.6, C | 45.7, C |
| 5 | 39.4, CH | 39.6, CH | 47.2, CH | 51.8, CH |
| 6 | 32.1, CH2 | 32.3CH2 | 32.3, CH2 | 72.1, CH |
| 7 | 174.1, C | 174.3, C | 172.6, C | 170.2, C |
| 8 | 81.4, C | 82.6, C | 94.0, C | 92.0, C |
| 9 | 58.0, CH | 58.5, CH | 55.8, CH | 55.2, CH |
| 10 | 47.6, C | 44.9, C | 51.1, C | 50.5, C |
| 11 | 69.0, CH | 69.2, CH | 69.0, CH | 21.8, CH2 |
| 12 | 36.2, CH2 | 36.0, CH2 | 34.0, CH2 | 34.2, CH2 |
| 13 | 41.8, C | 41.8, C | 41.2, C | 35.3, C |
| 14 | 71.3, C | 71.3, C | 71.3, C | 42.4, CH |
| 15 | 37.0, CH2 | 36.9, CH2 | 37.0, CH2 | 28.2, CH2 |
| 16 | 169.0, C | 170.1, C | 168.0, C | 169.3, C |
| 17 | 77.8, CH | 78.0, CH | 77.8, CH | 77.8, CH |
| 18 | 15.4, CH3 | 15.7, CH3 | 15.9, CH3 | 22.5, CH3 |
| 19 | 22.8, CH3 | 21.8, CH3 | 22.8, CH3 | 22.7, CH3 |
| 20 | 120.4, C | 120.5, C | 120.2, C | 121.1, C |
| 21 | 141.7, CH | 141.6, CH | 141.5, CH | 140.6, CH |
| 22 | 110.2, CH | 110.2, CH | 109.8, CH | 109.5, CH |
| 23 | 143.0, CH | 142.8, CH | 143.3, CH | 143.6, CH |
| 28 | 22.5, CH3 | 22.5, CH3 | 26.7, CH3 | 27.5, CH3 |
| 29 | 24.5, CH3 | 24.4, CH3 | 27.3, CH3 | 27.9, CH3 |
| 30 | 41.1, CH2 | 41.9, CH2 | 41.7, CH2 | 40.0, CH2 |
| 2-OAc | 175.3, C | — | — | — |
| 22.3, CH3 | — | — | — | |
| 3-OAc | 170.6, C | 171.5, C | 170.1, C | 170.1, C |
| 21.10, CH3 | 21.12, CH3 | 20.9, CH3 | 20.9, CH3 | |
| 6-OAc | — | — | — | 170.3, C |
| — | — | — | 21.0, CH3 | |
| 7-OCH3 | 52.2, CH3 | 52.1, CH3 | 52.1, CH3 | 52.9, CH3 |
| 11-OAc | 169.8, C | 169.8, C | 169.8, C | — |
| 21.08, CH3 | 21.07, CH3 | 21.2, CH3 | — |