Table 1.

Kinetic models of FTS based on cobalt catalyst using a fixed-bed reactor.

Catalyst	Operation conditions			Kinetic model	References
	P (Mpa)	T (°C)	H2/CO
La.Fe0.7.Co0.3/γ-Al2O3	1.0–2.0	240–300	1.0–2.0	$\frac{k_p{b}_{\mathit{CO}}{P}_{\mathit{CO}}{(b_{H2}{P}_{H2})}^{0.5}}{{(1+b_{\mathit{CO}}{P}_{\mathit{CO}}+{(b_{H2}{P}_{H2})}^{0.5})}^2}$	10
Industrial cobalt based	1.0–5.6	170–215	2.0–3.0	$\frac{K{P}_{\mathit{CO}}^{0.5}{P}_{H2}^{0.5}}{{(1+K{P}_{\mathit{CO}})}^2}$	11
Co//γ-Al2O3	0.2–0.8	190–260	2.0	$\frac{K{P}_{\mathit{CO}}{P}_{H2}}{{(1+a{P}_{\mathit{CO}}+b{P}_{H2}^{0.5})}^2}$	12
Co/TiO2	2.0265	180–240	1–3.5	$\frac{k{P}_{H2}^{0.74}{P}_{\mathit{CO}}}{{\left(1+a{P}_{\mathit{CO}}\right)}^2}$	13
Co-Ce/SiO2	0.1	200–300	1–3	$\frac{k{P}_{H_2}}{\left(1+a{P}_{\mathit{CO}}\right)}$	14
Co-Mn	0.1–1	190–250	1–2	$\frac{k{P}_{\text{CO}}{P}_{{\text{H}}_2}}{{\left(1+a{P}_{{\text{H}}_2}^{0\text{.5}}+b{P}_{\text{CO}}{P}_{{\text{H}}_2}^{0\text{.5}}\right)}^2}$	15
Co-Ni/SiO2	1–5	280–320	1–3	$\frac{k{P}_{H_2}^{0.5}{P}_{\text{CO}}}{{\left(1+a{P}_{\text{CO}}+b{P}_{H_2}^{0.5}+c{P}_{H_2}^{0.5}{P}_{\mathit{CO}}\right)}^2}$	16
Co-Mn-Ce/SiO2	0.1–0.6	250–350	1–2	$\frac{k{P}_{\text{CO}}{P}_{{\text{H}}_2}}{{\left(1+a{P}_{{\text{H}}_2}+b{P}_{\text{CO}}\right)}^2}$	17
Co-Re/ γ-Al2O3	2.0–2.2	210–230	1.12–2.55	$\frac{k_{P_{\mathit{CO}}}{P}_{H2}^{0.5}(1+k_{P_{H2}}{k}_{P_{H2O}})}{{(1+{\alpha }^{,}{P}_{\mathit{CO}}+b{P}_{H2}^{0.5}+f^{,}{P}_{H2O})}^2}$	18