Table 6.

Kinetic equation for Fischer –Tropsch synthesis reaction rate according to LHHW.

Model	Kinetic equation	Site balance
C-I1	$k{P}_{\text{CO}}/(1+a{P}_{\text{CO}}+b{P}_{{\text{H}}_2}^{0\text{.5}})$	s + COs + Hs
C-I2	$k{P}_{{\text{H}}_2}/{(1+a{P}_{\text{CO}}+b{P}_{{\text{H}}_2}^{0\text{.5}})}^2$	s + COs + Hs
C-I3	$k{P}_{\text{CO}}{P}_{{\text{H}}_2}^{0\text{.5}}/{(1+a{P}_{\text{CO}}+b{P}_{{\text{H}}_2}^{0\text{.5}})}^2$	s + COs + Hs
C-I3′	$k{P}_{\text{CO}}{P}_{{\text{H}}_2}^{0\text{.5}}/{(1+b{P}_{{\text{H}}_2}^{0\text{.5}})}^2$	s + Hs
C-I4	$k{P}_{\text{CO}}{P}_{{\text{H}}_2}/{(1+a{P}_{\text{CO}}+b{P}_{{\text{H}}_2}^{0\text{.5}})}^2$	s + COs + Hs
C-I4′	$k{P}_{\text{CO}}{P}_{{\text{H}}_2}/{(1+a{P}_{\text{CO}}{P}_{{\text{H}}_2}^{0\text{.5}})}^2$	s + HOCs
C-I5	$k{P}_{\text{CO}}{P}_{{\text{H}}_2}/{(1+a{P}_{\text{CO}})}^2$	s + COs
C-II1	$k{P}_{\text{CO}}/(1+a{P}_{\text{CO}}+b{P}_{{\text{H}}_2})$	s + COs + H2s
C-II2	$k{P}_{{\text{H}}_2}/(1+a{P}_{\text{CO}}+b{P}_{{\text{H}}_2})$	s + COs + H2s
C-II3	$k{P}_{\text{CO}}{P}_{{\text{H}}_2}/{(1+a{P}_{\text{CO}}+b{P}_{{\text{H}}_2})}^2$	s + COs + H2s
C-II4	$k{P}_{\text{CO}}{P}_{{\text{H}}_2}^2/{(1+a{P}_{\text{CO}}{P}_{{\text{H}}_2})}^2$	s + CH2Os
C-III1	$k{P}_{\text{CO}}/(1+a{P}_{\text{CO}})$	s + Cos
C-III2	$k{P}_{\text{CO}}{P}_{{\text{H}}_2}/(1+a{P}_{\text{CO}})$	s + Cos
C-III3	$k{P}_{\text{CO}}{P}_{{\text{H}}_2}^2/(1+a{P}_{\text{CO}})$	s + Cos
C-III3′	$k{P}_{\text{CO}}{P}_{{\text{H}}_2}^2/(1+a{P}_{\text{CO}}{P}_{{\text{H}}_2})$	s + CH2Os
C-IV2	$k{P}_{\text{CO}}{P}_{{\text{H}}_2}^{0\text{.5}}/(1+a{P}_{{\text{H}}_2}^{0\text{.5}})$	s + Hs
C-IV3	$k{P}_{\text{CO}}{P}_{{\text{H}}_2}/{(1+a{P}_{{\text{H}}_2}^{0\text{.5}}+b{P}_{\text{CO}}{P}_{{\text{H}}_2}^{0\text{.5}})}^2$	s + HOCs + Hs
C-V1	$k{P}_{{\text{H}}_2}/{(1+a{P}_{{\text{H}}_2}^{\text{o}.5})}^2$	s + Hs
C-V2	$k{P}_{\text{CO}}{P}_{{\text{H}}_2}/{(1+a{P}_{{\text{H}}_2}^{0\text{.5}})}^2$	s + Hs
C-V3	$k{P}_{\text{CO}}{P}_{{\text{H}}_2}^2/{(1+a{P}_{{\text{H}}_2}^{0\text{.5}}+b{P}_{\text{CO}}{P}_{{\text{H}}_2}^{0\text{.5}})}^3$	s + CH2Os + Hs
C-VI1	$k{P}_{{\text{H}}_2}/(1+a{P}_{{\text{H}}_2})$	s + H2s
C-VI2	$k{P}_{\text{CO}}{P}_{{\text{H}}_2}/(1+a{P}_{{\text{H}}_2})$	s + H2s
C-VII1	$k{P}_{\text{CO}}/{(1+a{P}_{\text{CO}}^{0\text{.5}}+b{P}_{{\text{H}}_2}^{0\text{.5}})}^2$	s + Cs + Os + Hs
C-VII2	$k{P}_{{\text{H}}_2}/{(1+a{P}_{\text{CO}}^{0\text{.5}})}^2$	s + Cs + Os
C-VII2′	$k{P}_{{\text{H}}_2}/{(1+a{P}_{\text{CO}}^{0\text{.5}}+b{P}_{{\text{H}}_2}^{0\text{.5}})}^2$	s + Cs + Os + Hs
C-VII3	$k{P}_{\text{CO}}^{0\text{.5}}{P}_{{\text{H}}_2}^{0\text{.5}}/{(1+a{P}_{\text{CO}}^{0\text{.5}}+b{P}_{{\text{H}}_2}^{0\text{.5}})}^2$	s + Cs + Os + Hs
C-VIII3	$k{P}_{\text{CO}}^{0\text{.5}}{P}_{{\text{H}}_2}/{(1+a{P}_{\text{CO}}^{0\text{.5}}+b{P}_{{\text{H}}_2})}^2$	s + Cs + Os + H2s
C-IX1	$k{P}_{\text{CO}}/{(1+a{P}_{\text{CO}}^{0\text{.5}})}^2$	s + Cs + Os
C-IX2	$k{P}_{{\text{H}}_2}{P}_{\text{CO}}^{0\text{.5}}/(1+a{P}_{\text{CO}}^{0\text{.5}})$	s + Cs + Os
C-X3	$k{P}_{\text{CO}}^{0\text{.5}}{P}_{{\text{H}}_2}/{(1+a{P}_{\text{CO}}^{0\text{.5}}+b{P}_{{\text{H}}_2}^{0\text{.5}})}^3$	s + Cs + Os + Hs