Table 7.
Kinetic and statistical parameters for each LHHW equation resulted from nonlinear regression fitting.
| Model | Kinetic parameter | Statically indicator | ||||
|---|---|---|---|---|---|---|
| k (x) (mol g−1 min−1 barx) | (x) (barx) | b (x) (barx) | R2 | RMSD | Variance | |
| C-I1 | 0.000901 (− 1) | − 0.128 (− 1) | − 0.0788 (− 1/2) | 0.987 | 0.00029 | 1.37E−06 |
| C-I2 | 0.000673 (− 1) | − 0.118 (− 1) | − 0.709 (− 1/2) | 0.978 | 0.00044 | 3.14E−06 |
| C-I3 | 0.000614 (− 3/2) | − 0.00748 (− 1) | − 0.852 (− 1/2) | 0.981 | 0.00040 | 2.63E−06 |
| C-I3′ | 0.00064 (− 3/2) | − 0.859 (− 1/2) | 0.981 | 0.00040 | 2.37E−06 | |
| C-I4 | 0.000935 (− 2) | 0.00972 (− 1) | − 0.842 (− 1/2) | 0.979 | 0.00043 | 2.96E−06 |
| C-I4′ | 0.00541 (− 2) | − 0.310 (− 3/2) | 0.784 | 0.00139 | 2.81E−05 | |
| C-I5 | 0.0146 (− 2) | − 0.0367 (− 1) | 0.746 | 0.00151 | 3.31E−05 | |
| C-II1 | 0.00124 (− 1) | − 0.211 (− 1) | − 0.673 (− 1) | 0.99 | 0.00029 | 1.42E−06 |
| C-II2 | 0.00195 (− 1) | − 0.293 (− 1) | − 0.547 (− 1) | 0.984 | 0.00037 | 2.31E−06 |
| C-II3 | 0.00216 (− 2) | − 0.0129 (− 1) | − 0.723 (− 1) | 0.981 | 0.00041 | 2.69E−06 |
| C-II4 | 0.00168 (− 3) | − 0.542 (− 2) | 0.964 | 0.00056 | 4.66E−06 | |
| C-III1 | 0.00574 (− 1) | − 0.31 (− 1) | 0.519 | 0.00208 | 6.28E−05 | |
| C-III2 | 0.0148 (− 2) | − 0.061 (− 1) | 0.746 | 0.00151 | 3.31E−05 | |
| C-III3 | 0.0224 (− 3) | 0.0587(− 1) | 0.962 | 0.000535 | 4.12E−06 | |
| C-III3′ | 0.0064 (− 3) | − 0.523 (− 1) | 0.993 | 0.00022 | 7.59E−07 | |
| C-IV2 | 0.00224 (− 3/2) | − 0.918(− 1/2) | 0.99 | 0.00026 | 1.04E−06 | |
| C-IV3 | 0.06 (− 2) | − 0.897 (− 1/2) | 0.247 (− 3/2) | 0.99 | 0.00019 | 6.27E−07 |
| C-V1 | 0.00176 (− 1) | − 0.787 (− 1/2) | 0.947 | 0.00064 | 5.82E−05 | |
| C-V2 | 0.00163 (− 2) | − 0.746 (− 1/2) | 0.994 | 0.00020 | 5.87E−05 | |
| C-V3 | 0.00346 (− 3) | − 0.436(− 1/2) | − 0.0312 (− 3/2) | 0.994 | 0.00020 | 6.75E−07 |
| C-VI1 | 0.0057 (− 1) | − 0.863 (− 1) | 0.92 | 0.00076 | 8.31E−06 | |
| C-VI2 | 0.0050 (− 2) | − 0.812 (− 1) | 0.99 | 0.00076 | 7.66E−07 | |
| C-VII1 | 0.00038 (− 1) | − 0.165 (− 1/2) | − 0.682 (− 1/2) | 0.996 | 0.00015 | 3.94E−07 |
| C-VII2 | 0.00342 (− 1) | − 0.502 (− 1/2) | 0.819 | 0.00117 | 1.97E−05 | |
| C-VII2′ | 0.00058 (− 1) | − 0.321 (− 1/2) | − 0.489 (− 1/2) | 0.996 | 0.00017 | 4.651E−07 |
| C-VII3 | 0.00048 (− 1) | − 0.244 (− 1/2) | − 0.584 (− 1/2) | 0.996 | 0.00015 | 4.04E−07 |
| C-VIII3 | 0.0012 (− 3/2) | − 0.332 (− 1/2) | − 0.400 (− 1) | 0.996 | 0.00015 | 4.05E−07 |
| C-IX1 | 0.00264(− 1) | − 0.416 (− 1/2) | 0.65 | 0.00163 | 3.82E−05 | |
| C-IX2 | 0.007 (− 3/2) | − 0.519 (− 1/2) | 0.834 | 0.00112 | 1.82E−05 | |
| C-X3 | 0.000435 (− 3/2) | − 0.0853 (− 1/2) | − 0.671 (− 1/2) | 0.977 | 0.000456 | 3.33E−06 |