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. 2024 May 30;146(23):16332–16339. doi: 10.1021/jacs.4c05358

Table 2. Photophysical Parameters of 3″ and 5a–5c.

  Δνa/cm–1 ΦFb ΦISCc τFd/ns kre/108 s–1 knrf/108 s–1
5a 364 0.88   4.9 1.8 0.24
5b 403 0.84 0.001 4.6 1.8 0.35
5c 344 0.84 0.002 4.1 2.0 0.39
3″ 284 0.76   3.6 2.1 0.67
a

Stokes shift.

b

Fluorescence quantum yield.

c

ISC quantum yield.

d

Fluorescence lifetime.

e

Radiative decay constant.

f

Nonradiative decay constant.