Table 2. Photophysical Parameters of 3″ and 5a–5c.
Δνa/cm–1 | ΦFb | ΦISCc | τFd/ns | kre/108 s–1 | knrf/108 s–1 | |
---|---|---|---|---|---|---|
5a | 364 | 0.88 | 4.9 | 1.8 | 0.24 | |
5b | 403 | 0.84 | 0.001 | 4.6 | 1.8 | 0.35 |
5c | 344 | 0.84 | 0.002 | 4.1 | 2.0 | 0.39 |
3″ | 284 | 0.76 | 3.6 | 2.1 | 0.67 |
Stokes shift.
Fluorescence quantum yield.
ISC quantum yield.
Fluorescence lifetime.
Radiative decay constant.
Nonradiative decay constant.