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. 2024 Jun 7;31(28):41221–41245. doi: 10.1007/s11356-024-33821-w

Table 3.

Thermodynamic parameters for the adsorption of ATP and EY dye onto NH₂-MIL-101(Fe)

Pollutant			Van’t Hoff
Pollutant	T (K)	ΔG° (kJ.mol⁻¹)	ΔS° (kJ^−1.mol⁻¹)	ΔH° (kJ.mol⁻¹)	K
ATP	283 293 303 313	-20.39 -20.92 -21.42 -21.95	52.88	5.428	5.80 5.38 4.98 4.66
EY dye	298 308 318 328	-16.74 -17.20 -17.59 -18.04	57.16	2.012	0.86 0.82 0.78 0.75
		Arrhenius	`	Modified Arrhenius
ATP	$E_{a} (kJ . {mol}^{- 1})$	5.428	$E_{a} (kJ . {mol}^{- 1})$	4.553
EY dye	$E_{a} (kJ . {mol}^{- 1})$	2.012	$E_{a} (kJ . {mol}^{- 1})$	1.624
ATP	$A ({dm}^{3} . {mol}^{- 1} S^{- 1})$	10.74552	$S^{*}$	0.025
EY dye	$A ({dm}^{3} . {mol}^{- 1} S^{- 1})$	6.87577	$S^{*}$	0.29
Bold refers to model name.