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. 2024 Jun 5;9(24):25902–25913. doi: 10.1021/acsomega.4c00391

Table 1. Qualitative (GC–MS) and Quantitative (GC–FID) Chemical Composition of G. cuicochensis and G. sancti-antonii EO on 5%-Phenyl-methylpolysiloxane and Polyethylene Glycol Stationary Phasesc.

no. compounds 5%-phenyl-methylpolysiloxane
polyethylene glycol
    LRIa LRIb G. cuicochensis
G. sancti-antonii
reference LRIa LRIb G. cuicochensis
G. sancti-antonii
reference
        % σ % σ       % σ % σ  
1 α-pinene 933 932 29.4 4.84 3.0 0.51 (19) 1016 1016 29.6 4.26 2.9 0.24 (20)
2 sabinene 974 969 1.9 0.43 0.4 0.07 (19) 1103 1100 1.9 0.27 0.4 0.04 (21)
3 β-pinene 979 974 2.1 0.32 12.9 1.86 (19) 1115 1116 2.0 0.29 12.1 1.21 (22)
4 myrcene 992 988 0.7 0.08 0.2 0.02 (19) 1161 1161 0.7 0.08 0.2 0.16 (23)
5 pentyl furan 995 984 0.2 0.07     (19) 1231 1230 0.2 0.06     (24)
6 n-decane 1000 1000     trace     1000 1000     0.2 0.02  
7 α-phellandrene 1009 1002 0.9 0.10     (19) 1155 1153 0.7 0.08     (25)
8 (2E,4E)-heptadienal 1014 1007 0.1 0.02     (19) 1460 1461 0.2 0.02     (26)
9 α-terpinene 1020 1014 0.4 0.03     (19) 1171 1173 0.1 0.02     (27)
10 p-cymene 1029 1020 0.5 0.08 trace   (19) 1263 1264 0.6 0.07 0.1 0.01 (28)
11 limonene 1032 1024 1.5 0.18 0.6 0.08 (19) 1190 1190 1.5 0.16 0.3 0.21 (29)
12 β-phellandrene 1034 1025 0.2 0.04 0.4 0.06 (19) 1199 1198 trace   0.4 0.04 (30)
13 (E)-β-ocimene 1051 1044 0.5 0.05     (19) 1250 1251 0.6 0.05     (31)
14 benzene acetaldehyde 1061 1036 0.1 0.01     (19) 1677 1669 trace       (32)
15 γ-terpinene 1062 1054 0.1 0.02     (19) 1238 1238 0.1 0.02     (33)
16 (2E)-octen-1-al 1074 1049 0.2 0.02     (19) 1422 1425 0.1 0.01     (34)
17 trans-linalool oxide (furanoid) 1082 1084 0.1 0.01     (19) 1466 1466 trace       (35)
18 terpinolene 1088 1086 0.1 0.01     (19) 1274 1274 0.1 0.01   - (36)
19 linalool 1110 1113 0.3 0.03 0.5 0.04 (37) 1553 1556 0.1 0.01 0.3 0.04 (38)
20 nonanal 1116 1100 1.4 0.11     (19) 1390 1390 1.1 0.07     (39)
21 (2E)-hexenyl propanoate 1116 1111     trace   (40) 1390 1392     0.3 0.04 (40)
22 α-campholenal 1138 1122 trace       (19) 1478 1485 0.1 0.01     (41)
23 (3Z)-hexenyl isobutanoate 1155 1142 0.1 0.01     (19) 1384 1385 0.3 0.03     (42)
24 (2E)-nonen-1-al 1175 1157 0.1 0.01     (19) 1527 1524 0.2 0.01     (35)
25 safranal 1178 1197 trace       (19) 1631 1622 0.2 0.01     (43)
26 p-mentha-1,5-dien-8-ol 1186 1166 0.2 0.02     (19) 1723 1723 0.1 0.01     (44)
27 terpinen-4-ol 1191 1184 0.5 0.04 0.2 0.03 (45) 1594 1594 0.7 0.04 0.2 0.03 (46)
28 n-dodecane 1200 1200 0.1 0.01       1200 1200 0.3 0.04      
29 p-cymen-8-ol 1202 1179 trace       (19) 1845 1845 0.1 0.01     (31)
30 myrtenol 1209 1194 0.1 0.01     (19) 1784 1786 trace       (47)
31 α-terpineol 1209 1207 -   0.3 0.06 (39) 1692 1692     0.2 0.04 (23)
32 decanal 1217 1214 0.2 0.01 trace   (48) 1494 1492 0.2 0.03 0.1 0.01 (49)
33 β-cyclocitral 1232 1217 0.1 0.01     (19) 1605 1606 0.1 0.01     (50)
34 trans-carveol 1235 1215 0.1 0.01     (19) 1830 1830 trace       (35)
35 geraniol 1265 1249 trace       (19) 1849 1849 0.2 0.01     (51)
36 piperitone 1272 1249 0.1 0.01     (19) 1710 1710 trace       (52)
37 2-(E)-decenal 1276 1260 0.1 0.01     (19) 1635 1630 0.2 0.01     (39)
38 nonanoic acid 1297 1267 0.1 0.01     (19)              
39 n-tridecane 1300 1300 0.1 0.01       1300 1300 0.1 0.01      
40 cis-pinocarvyl acetate 1305 1311 0.1 0.01     (19) 1639   0.1 0.01     §
41 undecanal 1318 1319 0.1 0.01 0.2 0.04 (53) 1580 1580 0.5 0.08 trace   (54)
42 p-vinylguaiacol 1327 1324 3.3 0.19 1.8 0.42 (55) 2189 2193 3.6 0.11 2.4 0.47 (56)
43 (2E,4E)-decadienal 1335 1315 0.3 0.01     (19) 1799 1795 0.3 0.05     (57)
44 α-copaene 1376 1374     2.8 0.61 (19) 1474 1477     2.6 0.23 (58)
45 α-ylangene 1377 1373 0.1 0.01     (19) 1474 1472 0.6 0.05     (25)
46 2-epi-α-funebrene 1388 1380     0.4 0.10 (19) 1724       1.0 0.12 §
47 β-cubebene 1389 1387     0.3 0.07 (19) 1523 1521     0.2 0.02 (59)
48 (Z)-β-damascenone 1390 1361     0.3 0.06 (19) 1806 1791     0.1 0.02 (60)
49 geranyl acetate 1390 1379 1.4 0.14     (19) 1756 1756 1.4 0.14     (61)
50 n-tetradecane 1400 1400 0.2 0.01       1400 1400 0.3 0.01      
51 α-gurjunene 1407 1409 0.2 0.02     (19) 1510 1511 0.3 0.01     (62)
52 undetermined (MW: 192) 1408       2.7 0.44   1882       2.4 0.21  
53 (E)-β-damascenone 1418 1416 0.4 0.03     (19)              
54 (E)-β-caryophyllene 1421 1421 2.1 0.20 1.8 0.40 (19) 1575 1575 2.4 0.24 1.6 0.18 (63)
55 β-copaene 1432 1430 0.1 0.01     (19) 1570 1567 0.1 0.01     (64)
56 β-gurjunene 1432 1431     0.3 0.06 (19) 1671 1655     0.5 0.07 (41)
57 cis-α-bergamotene 1434 1433     trace   (65) 1528 1530     0.7 0.06 (66)
58 (Z)-β-farnesene 1443 1440     0.2 0.04 (19) 1633 1632     0.2 0.03 (67)
59 myltayl-4(12)-ene 1447 1445 0.1 0.01     (19)              
60 trans-muurola-3,5-diene 1448 1451     trace   (19) 1611       0.1 0.02 §
61 (E)-β-farnesene 1456 1454     0.6 0.13 (19) 1665 1660     0.5 0.07 (68)
62 α-humulene 1458 1452 2.6 0.21 0.5 0.10 (19) 1647 1649 2.6 0.23 0.2 0.03 (69)
63 cis-cadina-1,(6),4-diene 1465 1461     0.2 0.05 (19) 1689       0.2 0.02 §
64 cis-muurola-4(14),5-diene 1466 1465 0.1 0.01     (19) 1523   trace       §
65 (E)-β-farnesene 1472 1454 0.3 0.05     (19) 1665 1664 0.1 0.01     (25)
66 dauca-5,8-diene 1475 1471     0.3 0.05 (19) 1642 1654     0.2 0.04 (70)
67 γ-muurolene 1480 1478 0.1 0.01     (19) 1671 1676 0.2 0.01     (71)
68 γ-curcumene 1482 1481 0.4 0.09 19.7 4.63 (19) 1682 1689 0.3 0.10 18.3 2.11 (72)
69 germacrene D 1486 1495 20.8 2.48 14.9 3.32 (19) 1689 1683 19.9 2.50 9.0 0.84 (73)
70 ar-curcumene 1487 1479         (19) 1763 1763     5.3 0.69 (74)
71 (E)-β-ionone 1492 1487 1.2 0.15     (19) 1922 1923 1.4 0.18     (22)
72 trans-muurola-4(14),5-diene 1497 1493 0.4 0.03     (19) 1695   trace       §
73 α-zingiberene 1500 1493 2.3 0.25     (19) 1714 1713 2.2 0.22     (75)
74 bicyclogermacrene 1500 1500     0.8 0.18   1712 1706     1.2 0.14 (76)
75 α-muurolene 1503 1500 0.1 0.01 3.8 1.01 (19) 1708 1700 0.1 0.01 1.9 0.22 (77)
76 3-methyl-phenyl ethyl butanoate 1504 1495         (78) 1960 1964     0.4 0.05 (74)
77 β-curcumene 1513 1514     1.1 0.26 (19) 1731 1733     1.0 0.12 (79)
78 γ-cadinene 1518 1513 0.3 0.03     (19) 1739 1738 trace       (79)
79 δ-cadinene 1523 1522 1.5 0.15 4.1 0.88 (19) 1742 1744 2.2 0.19 4.6 0.54 (44)
80 (E)-nerolidol 1570 1561 0.2 0.03     (19) 2042 2045 0.1 0.02     (80)
81 germacrene D-4-ol 1586 1583 0.5 0.11 0.8 0.37 (81) 2034 2035 0.7 0.09 0.5 0.07 (82)
82 spathulenol 1589 1577 0.9 0.09     (19) 2106 2106 0.9 0.08     (83)
83 caryophyllene oxide 1588 1588 0.9 0.10 0.6 0.15 (19) 1967 1968 0.5 0.05 0.5 0.08 (35)
84 n-hexadecane 1600 1600 0.1 0.03 0.2 0.04   1600 1600 0.1 0.01 0.2 0.03  
85 salvial-4(14)-en-1-one 1604 1594 0.2 0.06     (19) 1979 1995 0.1 0.01     (36)
86 ledol 1616 1616 0.7 0.07 0.1 0.02 (84) 2005 2014 0.1 0.01 0.1 0.03 (85)
87 humulene epoxide II 1623 1608 0.7 0.05     (19) 2009 2011 0.2 0.02     (44)
88 1-epi-cubenol 1639 1638     0.1 0.01 (26) 2044 2035     0.4 0.02 (86)
89 cis-cadin-4-en-7-ol 1639 1635 0.2 0.04     (87) 2044   0.3 0.03     §
90 epi-α-cadinol 1655 1652 0.8 0.09 1.0 0.48 (19) 2157 2154 0.7 0.07 0.1 0.01 (88)
91 epi-α-muurolol 1658 1640 0.8 0.10     (19) 2173 2176 0.9 0.11     (25)
92 α-muurolol 1660 1652 0.4 0.06 3.3 0.46 (89) 2187 2187 trace   2.4 0.44 (28)
93 α-cadinol 1670 1670 2.4 0.34 3.0 0.41 (90) 2211 2212 2.5 0.31 3.0 0.29 (76)
94 ar-turmerone 1679 1668 0.4 0.04     (19) 2226   0.1 0.01     §
95 undetermined (FW:220) 1682       3.1 0.47   2248       4.2 0.52  
96 n-heptadecane 1700 1700 0.2 0.03       1700 1700 0.2 0.01      
97 amorpha-4,9-dien-2-ol 1706 1700 0.3 0.04 0.1 0.01 (19) 2275   0.3 0.03 0.4 0.29 §
98 pentadecanal 1727 1724 0.9 0.08     (19) 2022 2024 1.3 0.09     (91)
99 (2Z,6E)-farnesol 1730 1722     trace   (19) 2280 2291     0.2 0.21 (92)
100 n-octadecane 1800 1800 0.1 0.02       1800 1800 0.9 0.13      
101 hexadecanal 1833 1828 0.1 0.01     (19) 2129 2132 0.2 0.02     (91)
102 (2E,6E)-farnesyl acetate 1843 1845 trace   0.1 0.07 (19) 2233 2234 0.1 0.01 0.4 0.17 (93)
103 6,10,14-trimethyl-2-pentadecanone 1856 1846 0.1 0.01     (19) 2122 2125 0.1 0.02     (80)
104 heptadecanal 1932 1932 0.2 0.04 0.2 0.02 (88) 2238 2247 0.5 0.05 0.5 0.03 (88)
105 1-eicosene 1995 1993     0.7 0.07 (19) 2047 2047     1.0 0.08 (94)
106 n-heneicosane 2100 2100 0.1 0.02 0.1 0.02   2100 2100 0.1 0.02 0.8 0.39  
107 1-octadecanol acetate 2194 2205     0.2 0.02 (95) 2529 2521     0.1 0.03 (96)
108 n-docosane 2200 2200 trace   trace     2200 2200 0.1 0.01 0.3 0.14  
109 1- tricosene 2295 2292     2.1 0.26 (19) 2356       2.0 0.13 §
110 n-tricosane 2300 2300 0.7 0.12 0.5 0.09   2300 2300 0.1 0.02 0.4 0.27  
111 1-tetracosene 2400 2402     1.5 0.33 (97) 2452       2.0 0.17 §
112 n-tetracosane 2400 2400 trace   0.3 0.06   2400 2400 0.3 0.06 0.2 0.10  
113 docosanal 2440 2434 0.1 0.03     (19) 2682   0.3 0.05     §
114 n-pentacosane 2500 2500 0.2 0.05 0.2 0.03   2500 2500 0.1 0.02 0.1 0.05  
115 1-pentacosene 2506 2496     0.1 0.01 (98) 2478 2488     0.1 0.03 (58)
116 n-hexacosane 2600 2600 0.3 0.07       2600 2600 0.3 0.06      
  monoterpene hydrocarbons     38.4   17.5         37.9   16.5    
  oxygenated monoterpenes     3.2   1.0         3.0   0.8    
  sesquiterpene hydrocarbons     31.7   52.1         31.0   49.6    
  oxygenated sesquiterpenes     9.5   12.2         7.7   12.4    
  others     11.7   10.8         14.2   13.7    
  total     94.5   93.6         93.8   93.0    
a

Calculated linear retention index (LRI).

b

Reference LRI; % = percent by weight of EO; σ = standard deviation; § = identification by mass spectrometer (MS) only; and trace = <0.01%.

c

Major components in at least one EO are reported in bold.