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. 2024 Jun 7;128(24):5823–5839. doi: 10.1021/acs.jpcb.4c01237

Table 1. g-values of the Glycyl Radical Signals in Various GREa.

enzyme family gav gx gy gz H/D exchange reference
pyruvate formate lyase PFL 2.0037 2.0047 2.0039 2.0025 yes (39,58)
anaerobic ribonucleotide reductase ARNR 2.0033 2.0043 2.0033 2.0023 no (5861)
benzylsuccinate synthase BSS 2.0034* 2.0045 2.0036 2.0022 yes (57,58,62)
N-acetylglycyl radical   2.0032 2.0045 2.0031 2.0020 no (58,63)
a

The values measured in X-band experiments are given as gav, and those under very-high-field conditions (525 GHz microwave frequency at up to 20 T magnetic flux density) as gx,y,z. An organic glycyl radical model is added for reference. *A deviating gav value of 2.0021 was initially reported57, which may be due to improper calibration.