Table 1. g-values of the Glycyl Radical Signals in Various GREa.
| enzyme | family | gav | gx | gy | gz | H/D exchange | reference |
|---|---|---|---|---|---|---|---|
| pyruvate formate lyase | PFL | 2.0037 | 2.0047 | 2.0039 | 2.0025 | yes | (39,58) |
| anaerobic ribonucleotide reductase | ARNR | 2.0033 | 2.0043 | 2.0033 | 2.0023 | no | (58−61) |
| benzylsuccinate synthase | BSS | 2.0034* | 2.0045 | 2.0036 | 2.0022 | yes | (57,58,62) |
| N-acetylglycyl radical | 2.0032 | 2.0045 | 2.0031 | 2.0020 | no | (58,63) |
The values measured in X-band experiments are given as gav, and those under very-high-field conditions (525 GHz microwave frequency at up to 20 T magnetic flux density) as gx,y,z. An organic glycyl radical model is added for reference. *A deviating gav value of 2.0021 was initially reported57, which may be due to improper calibration.