Table 4. Rate Coefficients (in Units of cm3 Molecule–1 s–1) for the Gas-Phase Reaction of OH Radicals with Alkenols vs Their Alkene Structural Homologues and Alkenols vs Their Saturated Alcohols Structural Homologues at a Temperature of 298 ± 4 K.
| alkenols | kOH × 1011 | alkenes | kOH × 1011 | kalkenol/kalkene | alcohols | kOH × 1011 | kalkenol/kalcohol |
|---|---|---|---|---|---|---|---|
| 2-propen-1-ol | 5.0021 | propene | 2.4421 | 2.05 | propan-1-ol | 0.5921 | 8.47 |
| 2-methyl-2-propen-1-ol | 9.0021 | 2-methylpropene | 5.1021 | 1.82 | 2-methylpropan-1-ol | 0.9721 | 9.59 |
| 3-buten-1-ol | 5.5021 | 1-butene | 3.1454 | 1.75 | butan-1-ol | 0.9121 | 6.04 |
| 2-buten-1-ol | 8.7021 | (Z/E)2-butene | 5.28/6.3121 | 1.65/1.38 | 9.56 | ||
| 3-methyl-2-buten-1-ol | 14.55a | 2-methyl-2-butene | 8.6945 | 1.67 | 3-methyl-butan-1-ol | 1.3955 | 10.47 |
| 3-methyl-3-buten-1-ol | 10.04a | 2-methyl-1-butene | 6.1043 | 1.65 | 7.22 | ||
| 3-methyl-3-buten-2-ol | 11.71a | 1.92 | 3-methyl-butan-2-ol | 1.2555 | 9.37 | ||
| 2-methyl-3-buten-2-ol | 6.23a | 3-methyl-1-butene | 3.1845 | 1.99 | 2-methyl-butan-2-ol | 0.3622 | 17.56 |
| 2-methyl-3-buten-1-ol | 5.31a | 1.67 | 2-methyl-butan-1-ol | ||||
| (Z)2-penten-1-ol | 11.7021 | Z-2-pentene | 6.5021 | 1.80 | pentan-1-ol | 1.1021 | 10.64 |
| (E)2-penten-1-ol | 6.7656 | E-2-pentene | 6.7021 | 1.01 | 6.15 | ||
| 1-penten-3-ol | 6.3321 | 1-pentene | 3.2221 | 1.97 | pentan-3-ol | 1.3021 | 4.87 |
| (Z)2-hexen-1-ol | 9.7721 | hexan-1-ol | 1.3021 | ||||
| (E)2-hexen-1-ol | 7.9321 | (E)2-hexene | 6.0857 | 1.30 | 6.10 | ||
| (Z)3-hexen-1-ol | 10.8021 | ||||||
| (E)3-hexen-1-ol | 9.7321 | (Z)3-hexene | 6.2758 | 1.72 | 8.31 | ||
| (Z)4-hexen-1-ol | 8.0821 | ||||||
| (E)4-hexen-1-ol | 7.1421 | ||||||
| 3-methyl-1-penten-3-ol | 6.2059 | 3-methylpentan-1-ol | |||||
| (Z)3-hepten-1-ol | 12.8060 | heptan-1-ol | 1.3021 | 9.85 | |||
| (Z)3-octen-1-ol | 14.9060 | octan-1-ol | 1.3021 | 11.46 |
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This work.