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. 2024 Jun 7;16(24):30900–30914. doi: 10.1021/acsami.4c05069

Table 6. Main Thermal Events Attributed to β-CD, MMC, MM (1:1), MM (2:1), FL (1:1), and FL (2:1).

  TGA and DTG
DTA
events
    events
 
compound Tinitial (°C) Tfinal (°C) Tmax (°C) Δm (%) tasks Tinitial (°C) Tfinal (°C) Tmax (°C) tasks
β-CD 58 108 83 15.0 dehydration 38 119 91 endothermic dehydration process
303 355 330 75.0 decomposition 299 360 330, 342 endothermic fusion and decomposition processes in successive stages of β-CD
345 646 501 10.0 394 700 571
MMC 32 110 78 25.0 dehydration 43 153 91 endothermic dehydration processes
111 130 121 5.0 decomposition
174 329 268 46.5 322 666 606 endothermic decomposition processes in successive stages
298
465 665 584 23.5
MM (1:1) 52 98 78 12.5 dehydration 33 115 85 endothermic dehydration process
120 197 161 21.7 decomposition 137 191 155 endothermic process of disruption of interactions between MMC and β-CD
295 387 344 27.3 241 566 439 exothermic process of disruption of interactions between MMC and β-CD
399 591 502 38.5 570 700 654 endothermic process of β-CD
MM (2:1) 53 97 78 10.0 dehydration 28 118 78 endothermic dehydration process
124 220 161 32.0 decomposition 133 171 155 endothermic process of MMC
316 573 339 57.0 228 594 408 exothermic process of disruption of interactions between MMC and β-CD
408
FL (1:1) 28 92 74,5 12.5 dehydration 28 112 78 endothermic dehydration process
126 197 157 21.5 decomposition 139 185 158 endothermic decomposition of MMC
285 402 347 36.0 227 663 380 exothermic process of disruption of interactions between MMC and β-CD
465 635 538 28.9 514
FL (2:1) 28 86 68 10.0 dehydration 28 112 74 endothermic dehydration process
117 205 169 30.0
301 388 345 21.1 decomposition 181 600 573 exothermic processes of disruption of interactions between MMC and β-CD
465 594 540 38.9 526