Extended Data Table 4.
Bile acid | Patients with GVHD N = 581 | Control N = 571 | p-value2 | q-value3 | Level of confidence6 |
---|---|---|---|---|---|
UDCA-sulfate4 | 1,929.0 (287.3, 7,522.3) | 15,357.8 (2,357.7, 34,033.4) | <0.001 | <0.001 | |
β-MCA4 | 0.3 (0.0, 6.5) | 8.1 (2.0, 21.2) | <0.001 | <0.001 | |
CA-sulfate4 | 3.9 (0.5, 17.4) | 45.2 (6.4, 243.2) | <0.001 | <0.001 | |
ω-MCA4 | 28.5 (0.0, 100.8) | 115.3 (31.4, 257.2) | <0.001 | <0.001 | |
γ-MCA5 | 0.0 (0.0, 136,156.2) | 161,338.0 (0.0, 364,832.0) | <0.001 | 0.001 | |
3-oxoCDCA5 | 0.0 (0.0, 0.0) | 69,977.0 (0.0, 712,188.0) | <0.001 | 0.001 | |
CDCA-sulfate4 | 87.8 (6.6, 742.0) | 756.5 (89.9, 3,279.4) | <0.001 | 0.002 | |
3-oxoCA5 | 26,856.5 (0.0, 386,074.8) | 297,807.0 (134,653.0, 1,765,809.0) | 0.001 | 0.004 | |
6α-THBA5 | 0.0 (0.0, 0.0) | 0.0 (0.0, 98,567.0) | 0.001 | 0.004 | |
7-oxoDCA5 | 0.0 (0.0, 2,538,904.5) | 937,617.0 (0.0, 23,199,642.0) | <0.001 | 0.004 | |
7-oxoLCA5 | 0.0 (0.0, 1,248,594.8) | 1,312,422.0 (61,782.0, 9,587,159.0) | <0.001 | 0.004 | |
DCA4 | 2.5 (0.2, 31.4) | 32.8 (4.0, 360.0) | 0.001 | 0.004 | |
cholenic acid5 | 0.0 (0.0, 0.0) | 0.0 (0.0, 72,294.0) | 0.002 | 0.007 | |
LCA-sulfate4 | 14.1 (2.9, 91.8) | 98.6 (9.6, 432.7) | 0.002 | 0.007 | |
CA4 | 2,443.2 (59.2, 15,819.0) | 14,881.8 (374.4, 33,058.8) | 0.004 | 0.011 | |
DCA-sulfate4 | 0.6 (0.0, 10.5) | 17.3 (0.5, 138.9) | 0.004 | 0.011 | |
isoCA5 | 0.0 (0.0, 217,816.0) | 111,039.0 (0.0, 1,769,979.0) | 0.005 | 0.011 | |
isoLCA5 | 0.0 (0.0, 0.0) | 0.0 (0.0, 179,311.0) | 0.005 | 0.011 | |
LCA4 | 2.8 (0.2, 11.0) | 6.8 (2.6, 204.3) | 0.004 | 0.011 | |
3oxoLCA5 | 0.0 (0.0, 0.0) | 0.0 (0.0, 1,953,269.0) | 0.007 | 0.015 | |
isoCDCA5 | 0.0 (0.0, 94,188.0) | 0.0 (0.0, 1,153,771.0) | 0.008 | 0.016 | |
ursocholic acid5 | 0.0 (0.0, 217,720.2) | 234,918.0 (0.0, 1,314,511.0) | 0.011 | 0.023 | |
CDCA4 | 830.7 (60.4, 3,860.2) | 2,903.2 (364.7, 14,684.4) | 0.012 | 0.023 | |
3-oxoDCA5 | 0.0 (0.0, 0.0) | 0.0 (0.0, 169,038.0) | 0.026 | 0.049 | |
GLCA-sulfate4 | 18.7 (7.6, 70.5) | 47.8 (12.2, 107.0) | 0.038 | 0.067 | |
isoDCA5 | 0.0 (0.0, 0.0) | 0.0 (0.0, 1,200,227.0) | 0.039 | 0.067 | |
12-oxoLCA5 | 0.0 (0.0, 0.0) | 0.0 (0.0, 126,673.0) | 0.064 | 0.11 | |
7,12-dioxoLCA5 | 0.0 (0.0, 0.0) | 0.0 (0.0, 55,133.0) | 0.092 | 0.15 | |
Gγ-MCA5 | 84,721.0 (0.0, 535,719.2) | 0.0 (0.0, 322,213.0) | 0.10 | 0.2 | |
GCA4 | 3,148.5 (244.6, 17,332.4) | 532.5 (69.2, 6,453.0) | 0.11 | 0.2 | |
UDCA4 | 10,716.5 (2,622.0, 29,154.2) | 22,632.5 (3,336.6, 46,019.2) | 0.2 | 0.3 | |
GLCA4 | 0.5 (0.4, 1.1) | 0.6 (0.4, 3.7) | 0.2 | 0.3 | |
TUDCA4 | 422.6 (37.6, 4,278.1) | 711.4 (207.0, 5,071.7) | 0.2 | 0.3 | |
TLCA4 | 0.7 (0.4, 1.6) | 1.3 (0.4, 6.1) | 0.3 | 0.4 | |
Tγ-MCA5 | 0.0 (0.0, 295,257.0) | 0.0 (0.0, 901,258.0) | 0.5 | 0.6 | |
TCDCA4 | 391.9 (22.4, 2,279.0) | 312.6 (61.4, 2,281.3) | 0.6 | 0.7 | |
TCA4 | 1,342.8 (180.1, 5,517.0) | 688.7 (84.0, 4,786.7) | 0.6 | 0.7 | |
GCDCA4 | 982.3 (119.0, 10,338.7) | 502.7 (126.5, 5,975.0) | 0.6 | 0.7 | |
TDCA4 | 1.0 (0.0, 5.7) | 1.1 (0.0, 28.5) | 0.7 | 0.8 | |
GUDCA-sulfate4 | 1,535.2 (97.7, 13,577.0) | 1,809.3 (52.7, 13,547.9) | 0.7 | 0.8 | |
GCDCA-sulfate4 | 177.6 (26.6, 1,201.0) | 222.6 (3.7, 1,484.6) | 0.8 | 0.8 | |
GCA-sulfate4 | 21.2 (4.4, 64.9) | 30.7 (1.0, 87.1) | 0.8 | 0.9 | |
GDCA4 | 4.0 (0.0, 22.5) | 2.3 (0.0, 33.0) | >0.9 | >0.9 | |
GDCA-sulfate4 | 2.8 (0.2, 18.7) | 4.4 (0.0, 21.5) | >0.9 | >0.9 | |
GUDCA4 | 3,392.3 (324.6, 26,282.2) | 1,973.7 (246.2, 25,565.6) | >0.9 | >0.9 |
Median (IGR);
Wilcoxon rank sum test;
False discovery rate correction for multiple testing;
Measured in pmol/mg;
Measured in AUC,
Schymanski, E. L. et al. Identifying Small Molecules via High-Resolution Mass Spectrometry: Communicating Confidence. Environ. Sci. Technol. 48, 2097–2098 (2014).