Table 3.
Cannabinoid profile of hemp extracts.
| No | Proposed Identity | TR (min) | HRMS (m/z) | MF | HRMS/MS (m/z) | Sample | Ref. |
|---|---|---|---|---|---|---|---|
| 1 | Cannabichromanonic acid | 4.1 | 377.1974 | C21H28O6 | 301.1463, 283.1369, 273.1480, 255.1386, 245.1524 | HTE, HSE | [29] |
| 2 | Cannabielsoic acid | 5.2 | 375.2153 | C22H30O5 | 357.2051, 339.1941, 297.1521, 275.1269, 245.1509, 233.1140, 219.0995, 207.1004 | HTE, HSE, HWE | [29,30] |
| 3 | Cannabinodiolic acid | 5.9 | 355.1892 | C22H26O4 | 323.1605, 313.1776, 299.1625, 273.1465, 253.0850, 239.1048, 225.0896, 211.0977, 197.0944, 187.0741 | HTE, HSE, HWE | [29,30,32] |
| 4 | Cannabitriolic acid | 7.0 | 391.2091 | C22H30O6 | 301.1454, 283.1310, 273.1460, 255.1353, 245.1510, 235.0933, 217.0834 | HTE, HSE, HWE | [29] |
| 5 | Cannabidivarinic acid * | 8.2 | 331.1893 | C20H26O4 | 313,1781, 295.0933, 273.1487, 255.1346, 215.1534, 193.1198, 173.0941, 145.0996, 141.0894 | HTE, HSE, HWE | [29,30,32] |
| 6 | Cannabitriol | 10.2 | 347.2195 | C21H30O4 | 291.1574, 271.1515, 245.1521, 231.1353, 217.1195, 207.1053, 201.0889, 193.1195 | HTE, HSE, HWE | [29,30] |
| 7 | Cannabinodiol | 11.6 | 311.1995 | C21H26O2 | 281.1500, 231.1358, 225.0907, 217, 1210, 213.0901, 199.0744, 193.1200, 173.0945, 165.0893, 145.0978 | HTE, HSE, HWE | [29,30] |
| 8 | Epoxycannabigerol | 12.7 | 333.2339 | C21H32O3 | 273.1846, 259.1678, 247.1653, 193.1203, 177.1216, 135.1143, 123.0422 | HTE, HSE, HWE | [29,30] |
| 9 | Cannabidivarin * | 13.9 | 287.2002 | C19H26O2 | 231.1375, 219.136, 203.1074, 189.0911, 179.059, 165.0907, 123.0439 | HTE, HSE, HWE | [29,30,31] |
| 10 | Cannabielsoin | 15.3 | 331.2249 | C21H30O3 | 271.1670, 231.1360, 193.1204, 135.0426, 109.1000 | HTE, HSE, HWE | [29,30,31] |
| 11 | Δ9/Δ8-Tetrahydrocannabinolic acid | 16.5 | 345.2059 | C21H28O4 | 327.1949, 297.1498, 285.1515, 268.1521, 229.0866, 211.0762, 197.0623 | HTE, HSE, HWE | [29,30,31,32] |
| 12 | Hydroxycannabinol | 18.2 | 327.1978 | C21H26O3 | 313.2111, 287.1663, 271.1692, 259.1686, 247.1362, 231.1355, 211.0768, 201.0899, 193.1208 | HTE, HSE, HWE | [30] |
| 13 | Cannabicoumaronic acid | 20.6 | 373.1988 | C22H28O5 | 299.1685, 273.1462, 233.1158, 193.1122, 183.0999, 147.0787, 127.0376 | HTE, HSE | [29] |
| 14 | Cannabidiolic acid * | 21.5 | 359.2201 | C22H30O4 | 341.2096, 299.1638, 285.1469, 273.1474, 261.1467, 233.1159, 219.1001 | HTE, HSE, HWE | [29,30,32] |
| 15 | Cannabidiol * | 22.6 | 315.2311 | C21H30O2 | 273.1825, 259.1677, 247.1676, 231.1373, 217.1209, 207.21363, 193.1209, 177.1189, 165.0901, 151.0744, 137.0588, 135.1155, 123.0424, 107.0844 | HTE, HSE, HWE | [29,30,31,32] |
| 16 | Cannabinol * | 26.1 | 311.2001 | C21H26O2 | 273.1866, 259.1670, 241.1544, 231.1374, 217.1217, 193.1213, 135.1154, 123.0433, 107.0848 | HTE, HSE, HWE | [29,30,31,32] |
| 17 | Dehydrocannabifuran | 29.7 | 309.1829 | C21H24O2 | 294.1607, 281.1576, 253.1205, 238.0974, 235.1106, 225.1198 | HTE, HSE | [29,30] |
| 18 | Δ9/Δ8-Tetrahydrocannabinol * | 32.2 | 315.2304 | C21H30O2 | 273.1844, 259.1680, 247.1673, 231.1377, 217.125, 207.1355, 193.1211, 135.1158, 123.0433, 107.847 | HTE, HSE, HWE | [29,30,31,32] |
| 19 | Cannabicoumaronone | 33.3 | 329.2095 | C21H28O3 | 287.1522, 273.1444, 259.1655, 247.1320, 229.0827, 209.1138, 153.0543 | HTE, HSE | [30] |
| 20 | Cannabicyclol * | 38.1 | 315.2308 | C21H30O2 | 273.1792, 259.1681, 247.1697, 233.1519, 217.1224, 207.1359, 193.1208, 177.1217, 135.1160, 123.0431 | HTE, HSE, HWE | [29,30,31] |
| 21 | Cannabichromene * | 39.1 | 315.2316 | C21H30O2 | 259.1659, 247.1670, 231.1372, 217.1351, 193.1193, 177.1175, 165.0884, 151.0731, 135.1141, 123.0420 | HTE, HSE | [29,30,31] |
* confirmed by standard.