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. 2024 Jun 3;10(6):1251–1261. doi: 10.1021/acscentsci.4c00121

Figure 5.

Figure 5

(a–c) Titration of 0–2 molar equiv of pyrene to 1.0 mM FeTetraPP: (a) UV–vis spectra of the Q-band region upon titration. Conditions: 0.1 M TBAPF6 in DMF, 1 mm path length. (b) CVs upon titration. (c) Observed rate constants (kobs) at each pyrene concentration. Conditions: 10 mM PhOH, 0.1 M TBAPF6 in CO2-saturated DMF, and 100 mV/s scan rate. (d–f) Titration of 0–0.4 molar equiv of AgPF6 to 0.5 mM FeTriPP: (a) UV–vis spectra of the Q-band region upon titration. Conditions: 0.1 M TBAPF6 in Ar-saturated DMF, 1 mm path length. (b) CVs upon titration. (c) Observed rate constants (kobs) for each titration of AgPF6. Conditions: 10 mM PhOH, 0.1 M TBAPF6 in CO2-saturated DMF, 100 mV/s scan rate.