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. 2024 May 28;2(6):1188–1197. doi: 10.1021/acsaom.4c00138

Table 3. Surface Profiles of the Examined Gratings, Diffraction Efficiencies Calculated with Raman–Nath Theory and Associated with Surface Heights, and Experimentally Measured Diffraction Efficiencies in the First Diffraction Ordera.

period (μm) height (nm) theory η0 (%) theory η1 (%) experiment η1 (%)
2.1 120 97.2 1.4 0.74 ± 0.04
7.2 210 91.7 4.1 3.6 ± 0.6
7.9 400 72.4 13.2 14.4 ± 3.3
8.0 490 61.0 18.3 17.3 ± 1.3
8.0 530 55.7 20.6 18.7 ± 1.6
a

Grating periods and heights were determined by AFM measurements.