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. 2024 Jun 21;9(26):28637–28647. doi: 10.1021/acsomega.4c02827

Table 1. Porosity Obtained via N2 Sorption Experiments and Metal Composition Obtained via ICP-OES of the Calcined Catalystsa.

catalyst N2 sorption
metal contentd
Pt/Nid mole ratio
  SBET (m2 g–1)a Vp (cm3 g–1)b Dp (nm)c Ni (wt %) Pt (wt %)  
Ni/Al2O3 187 0.50 7.4 9.69 0  
Pt/Al2O3 207 0.51 7.4 0 10.58  
Ni1Pt0.004/Al2O3 164 0.42 7.4 9.6 0.126 0.004
Ni1Pt0.007/Al2O3 148 0.40 7.4 10.16 0.242 0.007
Ni1Pt0.015/Al2O3 149 0.38 7.4 11.54 0.584 0.015
a

SBET obtained from the adsorption branch of the N2 isotherm.

b

Vp calculated from N2 adsorption at a relative pressure of ∼0.990.

c

Dp obtained from the desorption branch via the BJH method.

d

Metal composition determined via ICP-OES analysis.