Table 1. Experimental details.

Crystal data
Chemical formula	2C8H9NS·C6F4I2
M r	704.30
Crystal system, space group	Monoclinic, P21/c
Temperature (K)	100
a, b, c (Å)	11.184 (2), 5.2951 (6), 20.544 (3)
β (°)	96.137 (6)
V (Å3)	1209.7 (3)
Z	2
Radiation type	Mo Kα
μ (mm−1)	2.82
Crystal size (mm)	0.25 × 0.23 × 0.07
Data collection
Diffractometer	Bruker APEXII CCD
Absorption correction	Multi-scan (SADABS; Krause et al., 2015 ▸)
Tmin, Tmax	0.468, 0.567
No. of measured, independent and observed [I > 2σ(I)] reflections	91740, 5719, 5342
R int	0.036
(sin θ/λ)max (Å−1)	0.827
Refinement
R[F2 > 2σ(F2)], wR(F2), S	0.019, 0.047, 1.12
No. of reflections	5719
No. of parameters	181
H-atom treatment	All H-atom parameters refined
Δρmax, Δρmin (e Å−3)	0.91, −0.73

Computer programs: APEX2 and SAINT (Bruker, 2016 ▸), SHELXT (Sheldrick, 2015a ▸), SHELXL (Sheldrick, 2015b ▸) and OLEX2 (Dolomanov et al., 2009 ▸).