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The schematic representations of (a) bpydc moiety rotation and (b) gas diffusion in MOF-253. The brown, red, pink, indigo, gray, and green denote carbon, oxygen, hydrogen, nitrogen, palladium, and chlorine atoms, respectively. The red and blue curved arrows (left) suggest that the two bpydc moieties’ rotations do not necessarily correlate. The color blocks (right) denote the probability of guest molecule diffusion projected in a two-dimensional perspective.
