Table 6.
Compounds | KI1 | KI2 | Relative Concentration (ng/g) |
p-Value4 | Aroma description5 | |
---|---|---|---|---|---|---|
Control3 | PB4 | |||||
Acids (4) | ||||||
dodecanoic acid | 1582 | 1584 | 753.25 ± 18.10b | 1291.50 ± 56.91a | ⁎⁎ | fat, fruit |
hexanoic acid | 992 | 992 | ND | 698.06 ± 40.84 | ⁎⁎⁎ | cheese, fermented, pungent |
nonanoic acid | 1285 | 1284 | ND | 577.49 ± 35.47 | ⁎⁎⁎ | fat, green |
octanoic acid | 1186 | 1186 | ND | 2218.48 ± 81.62 | ⁎⁎⁎ | cheese, fat, fermented |
Alcohols (5) | ||||||
1-heptanol | 982 | 982 | ND | 19.83 ± 0.34 | ⁎⁎⁎ | green, wood |
1-hexanol | 887 | 887 | 199.52 ± 2.72b | 639.91 ± 53.13a | ⁎⁎ | bread, flower, fruit, grass, green |
1-octanol | 1089 | 1089 | ND | 806.66 ± 40.93 | ⁎⁎⁎ | citrus, fat, fruit, green |
1-pentanol | 755 | 755 | ND | 373.41 ± 9.06 | ⁎⁎⁎ | almond, balsamic, fruit, green |
2,3-butanediol | 824 | 828 | ND | 171.19 ± 10.52 | ⁎⁎⁎ | cream, floral, fruit, herb |
Aldehydes (2) | ||||||
benzaldehyde | 982 | 982 | 256.88 ± 12.80a | 116.77 ± 6.53 b | ⁎⁎ | almond, berry, bitter, bitter almond, burnt sugar |
nonanal | 1126 | 1126 | 81.91 ± 6.49a | 33.76 ± 1.48b | ⁎⁎ | citrus, cucumber, fat, floral, green |
Esters (7) | ||||||
ethyl decanoate | 1407 | 1419 | ND | 53.36 ± 1.47 | ⁎⁎⁎ | brandy, burnt, fruit, geranium, grape |
ethyl dodecanoate | 1603 | 1621 | ND | 24.32 ± 1.49 | ⁎⁎⁎ | cream, floral, fruit, green apple, leaf |
ethyl octanoate | 1215 | 1218 | 66.58 ± 1.57b | 180.55 ± 2.79a | ⁎⁎ | apricot, banana, brandy, fresh, fruit |
methyl butanoate | 745 | 742 | ND | 144.46 ± 10.09 | ⁎⁎⁎ | apple, banana, cheese, floral |
methyl dodecanoate | 1533 | 1551 | ND | 83.65 ± 6.70 | ⁎⁎⁎ | coconut, fat |
methyl hexanoate | 938 | 945 | ND | 106.08 ± 3.70 | ⁎⁎⁎ | fresh, fruit, pineapple, sweet |
methyl octanoate | 1138 | 1146 | 79.37 ± 3.16b | 589.47 ± 42.92a | ⁎⁎ | fruit, orange, sweet, wine |
Furan (1) | ||||||
2-pentylfuran | 1012 | 1011 | 1025.61 ± 45.10 | 916.53 ± 51.29 | NS | butter, floral, fruit, green, green bean |
Hydrocarbon (1) | ||||||
o-xylene | 911 | 912 | 1.95 ± 0.03b | 2.34 ± 0.06a | ⁎⁎ | geranium |
Ketones (4) | ||||||
(E,E)-3,5-octadien-2-one | 1107 | 1114 | ND | 181.23 ± 3.80 | – | almond, balsamic, dill, sweet, vanilla |
2-heptanone | 908 | 908 | 868.00 ± 25.14a | 512.45 ± 22.32b | ⁎⁎ | bell pepper, blue cheese, cinnamon, fruit, green |
2-nonanone | 1104 | 1112 | 1067.57 ± 32.71b | 1314.18 ± 45.90a | ⁎⁎ | fragant, fruit, green, hot milk, oil |
2-undecanone | 1315 | 1317 | 1203.13 ± 42.25b | 1451.22 ± 49.87a | ⁎⁎ | fresh, green, orange, pineapple, rose |
Lactones (2) | ||||||
5-hydroxydecanoic acid lactone | 1526 | 1531 | 38.25 ± 0.93b | 57.89 ± 0.94a | ⁎⁎ | apricot, butter, coconut, peach |
5-hydroxyoctanoic acid lactone | 1306 | 1314 | 157.73 ± 8.90b | 258.93 ± 15.08a | ⁎⁎ | butter, coconut, peach |
Phenol (1) | ||||||
2,6-di-tert-butyl-4-methylphenol | 1545 | 1548 | 15.04 ± 0.17b | 42.30 ± 1.34a | ⁎⁎ | toasted cereal |
Pyran (1) | ||||||
maltol | 1139 | 1138 | 14.37 ± 0.75b | 24.73 ± 0.65a | ⁎⁎ | butterscotch, caramel, cotton candy, malt, roasted bread |
Pyrazines (2) | ||||||
2,5-dimethylpyrazine | 932 | 932 | 46.67 ± 1.04b | 51.88 ± 1.47a | ⁎⁎ | cocoa, coffee |
3-ethyl-2,5-dimethylpyrazine | 1099 | 1100 | 42.65 ± 0.41b | 65.74 ± 4.00a | ⁎ | broth, chocolate, earth, must, potato |
NS, not significant.
ND, not detected.
NS: p > 0.05.
6All values are presented as mean ± standard deviation (n = 3).
Kovats index obtained from NIST available at https://webbook.nist.gov/chemistry/cas-ser/ for HP-5MS columns or equivalents.
Kovats index calculated using n-alkanes for the HP-5MS column.
Control, untreated; PB4, plant-based patty supplemented with 20 g biji powder.
Values with different uppercase letters in the same row are significantly different according to Student's t-test (p < 0.05).
p < 0.001.
p < 0.01.
p < 0.05.
Aroma character from https://www.vcf-online.nl/VcfCompoundSearch.cfm.