Table 1.
g-values and 9.4 Tesla electron spin resonances of various polarizing agents
| Polarizing Agent | Solvent | giso | (MHz) |
|---|---|---|---|
| BDPA-d27 | toluene | 2.0025* | 0 |
| galvinoxyl | toluene | 2.0044 | 250 |
| N@C60 | CCl4 | 2.0022* | 48 |
| N@C60 | CHCl3 | 2.0022* | 48 |
| TEMPONE-15N-d16 | toluene | 2.0059 | 447 |
| TEMPONE-15N-d16 | CCl4 | 2.0062 | 486 |
| TEMPONE-15N-d16 | CHCl3 | 2.0060 | 461 |
| TEMPONE-15N-d16 | H2O | 2.0057 | 421 |
Isotropic g-values of various PAs in selected solvents corresponding resonance frequency shifts with respect to that of BDPA in toluene at 9.4 T. The g-reference radicals53 in the corresponding solvents are indicated by an asterisk. N@C60 was calibrated in-house to a carbon fiber52. Precision of giso is 50 ppm. Data shown in Fig. 1c and Supplementary Fig. 17. Source data are provided as a Source Data file60.