Table 2.
P | PB1 | PB2 | PB3 | |
---|---|---|---|---|
qe,exp (mg/g) | 100.500 | 157.860 | 150.400 | 144.100 |
Lagergren model | ||||
qe (mg/g) a | 94.960 | 148.779 | 142.18 | 136.109 |
k1 × 102 (min−1) b | 3.024 | 3.984 | 3.767 | 3.330 |
R2 c | 0.970 | 0.968 | 0.970 | 0.971 |
χ2 d | 38.626 | 92.238 | 79.409 | 72.246 |
Ho model | ||||
qe (mg/g) a | 108.280 | 163.543 | 156.750 | 151.615 |
k2 × 104 (g/mg·min) e | 3.385 | 3.247 | 3.175 | 2.812 |
R2 c | 0.992 | 0.996 | 0.996 | 0.996 |
χ2 d | 9.961 | 12.427 | 10.369 | 10.123 |
Elovich model | ||||
α (mg/g·min) f | 7.593 | 22.864 | 19.550 | 14.577 |
β (g/mg) g | 0.044 | 0.034 | 0.035 | 0.035 |
R2 c | 0.994 | 0.992 | 0.992 | 0.994 |
χ2 d | 8.015 | 24.189 | 22.467 | 15.626 |
a qe—the amount of DCH sorbed onto the microparticles at equilibrium; b k1—the rate constant of the pseudo-first-order model; c R2—correlation coefficient; d χ2—chi-square test; e k2—the rate constant of the pseudo-second-order model; f α—the initial sorption rate; g β—the desorption constant.