Table 5.
PB1 | PB2 | PB3 | |||||||
---|---|---|---|---|---|---|---|---|---|
T (K) | 298 | 303 | 308 | 298 | 303 | 308 | 298 | 303 | 308 |
Langmuir model | |||||||||
qm (mg/g) a | 142.81 | 153.27 | 160.48 | 139.50 | 150.96 | 154.29 | 138.14 | 143.58 | 148.17 |
KL (L/g) b | 45.410 | 51.616 | 60.121 | 28.999 | 34.989 | 43.831 | 28.806 | 32.678 | 37.527 |
R2 c | 0.997 | 0.996 | 0.996 | 0.995 | 0.996 | 0.997 | 0.995 | 0.995 | 0.997 |
χ2 d | 0.167 | 0.246 | 0.243 | 0.475 | 0.430 | 0.224 | 0.468 | 0.464 | 0.288 |
Freundlich model | |||||||||
KF (L/g) e | 142.34 | 153.21 | 160.77 | 138.07 | 150.26 | 150.04 | 136.72 | 142.57 | 147.54 |
1/nF f | 0.071 | 0.067 | 0.061 | 0.101 | 0.091 | 0.077 | 0.101 | 0.094 | 0.085 |
R2 c | 0.955 | 0.953 | 0.953 | 0.948 | 0.959 | 0.947 | 0.963 | 0.962 | 0.957 |
χ2 d | 2.857 | 3.239 | 3.210 | 5.404 | 4.398 | 4.703 | 3.792 | 3.779 | 4.054 |
Dubinin-Radushkevich model | |||||||||
qm (mg/g) a | 142.15 | 152.77 | 160.15 | 138.16 | 149.94 | 153.62 | 136.79 | 142.45 | 147.26 |
E (kJ/mol) g | 9.739 | 10.417 | 11.273 | 8.021 | 8.804 | 9.848 | 8.003 | 8.573 | 9.232 |
R2 c | 0.999 | 0.998 | 0.999 | 0.997 | 0.998 | 0.999 | 0.997 | 0.998 | 0.999 |
χ2 d | 0.019 | 0.090 | 0.052 | 0.279 | 0.165 | 0.046 | 0.272 | 0.231 | 0.052 |
a qm—the maximum sorption capacity; b KL—the Langmuir constant; c R2—correlation coefficient; d χ2—chi-square test; e KF—the Freundlich constant; f nF—empirical constant; g E—sorption energy.