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1D tape in the crystal structure of solvatomorph 7·2DMF formed by the [Cu(ClO4)2(LH)4] molecules via N1A—H1A⋯O4perchlorate synthons along the b axis. The DMF solvents are only terminally hydrogen-bonded to the host complexes. Atoms generated by symmetry operations have been included, but have been labelled identically to the asymmetric unit.
