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. 2024 Jul 24;146(31):21280–21295. doi: 10.1021/jacs.3c11678

Figure 1.

Figure 1

Molecular structures of reported exchange-coupled actinide-based single-molecule magnets known to exhibit magnetic blocking, the year they were reported, and their 100-s blocking temperatures: {[UO2(salen)]2Mn(Py)3}6 (left),44 {[UO2(Mesaldien)][Mn(TPA)I]2}I (middle),45 and, from this work, (CpiPr5)3U3Cl6 (right). Orange, teal, red, blue, gray, purple, and green spheres represent U, Mn, O, N, C, I, and Cl atoms, respectively; H atoms and an outer-sphere I counterion are omitted for clarity.