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. 2024 Jul 24;146(31):21280–21295. doi: 10.1021/jacs.3c11678

Table 1. Selected Average Bond Distances (Å) and Angles (Deg) for (CpiPr5)3U3Cl6 (1-Cl), (CpiPr5)3U3Br6 (1-Br), and (CpiPr5)3U3I6 (1-I)a.

  1-Cl 1-Br 1-I
U···U 4.1946(7) 4.3762(5) 4.5700(5)
U–CpiPr5(cent) 2.4836(5) 2.5046(4) 2.4806(4)
U–X 2.812(1) 2.9677(7) 3.1914(8)
U–X–U 96.48(4) 95.01(2) 91.46(2)
X–U–CpiPr5(cent) 119.83(3) 119.24(2) 117.33(2)
a

The standard deviation of the average value was estimated from Inline graphic, where σi is the standard deviation of each bond distance (or angle) i and N is the number of distances (or angles) averaged.