Table 1. Selected Average Bond Distances (Å) and Angles (Deg) for (CpiPr5)3U3Cl6 (1-Cl), (CpiPr5)3U3Br6 (1-Br), and (CpiPr5)3U3I6 (1-I)a.
1-Cl | 1-Br | 1-I | |
---|---|---|---|
U···U | 4.1946(7) | 4.3762(5) | 4.5700(5) |
U–CpiPr5(cent) | 2.4836(5) | 2.5046(4) | 2.4806(4) |
U–X | 2.812(1) | 2.9677(7) | 3.1914(8) |
U–X–U | 96.48(4) | 95.01(2) | 91.46(2) |
X–U–CpiPr5(cent) | 119.83(3) | 119.24(2) | 117.33(2) |
The standard deviation of the average value was estimated from , where σi is the standard deviation of each bond distance (or angle) i and N is the number of distances (or angles) averaged.