Table 7.
| critical parameters | ||||||||
|
| ||||||||
| Tc/K | ρc/mol·L−1 | pc/MPa | ||||||
| 444.5 | 3.044 | 2.903 | ||||||
| parameters of the ideal-gas part of the equation of state (eqs 10–11) | ||||||||
|
| ||||||||
| i | νi | ui/K | ||||||
| 1 | 20.2 | 736.0 | ||||||
| 2 | 5.275 | 2299.0 | ||||||
| parameters to the residual part of the equation of state (eq 12); parameters not listed are not present for that value of k | ||||||||
|
| ||||||||
| k | Nk | tk | dk | lk | ηk | βk | γk | εk |
| 1 | 0.036673095 | 1.0 | 4 | |||||
| 2 | 1.1956619 | 0.26 | 1 | |||||
| 3 | −1.8462376 | 1.0 | 1 | |||||
| 4 | −0.60599297 | 1.0 | 2 | |||||
| 5 | 0.24973833 | 0.515 | 3 | |||||
| 6 | −1.2548278 | 2.6 | 1 | 2 | ||||
| 7 | −1.4389612 | 3.0 | 3 | 2 | ||||
| 8 | 0.35168887 | 0.74 | 2 | 1 | ||||
| 9 | −0.82104051 | 2.68 | 2 | 2 | ||||
| 10 | −0.031747538 | 0.96 | 7 | 1 | ||||
| 11 | 1.0281388 | 1.06 | 1 | 0.746 | 1.118 | 0.962 | 1.225 | |
| 12 | 0.21094074 | 3.4 | 1 | 2.406 | 3.065 | 1.111 | 0.161 | |
| 13 | 0.701701 | 1.617 | 3 | 0.7804 | 0.7274 | 1.135 | 1.231 | |
| 14 | 0.24638528 | 1.865 | 2 | 1.25 | 0.8435 | 1.163 | 1.395 | |
| 15 | −1.5295034 | 1.737 | 3 | 0.6826 | 0.6754 | 0.969 | 0.9072 | |
| 16 | 0.33424978 | 3.29 | 2 | 1.677 | 0.436 | 1.286 | 0.958 | |
| 17 | 1.011324 | 1.242 | 2 | 1.762 | 3.808 | 1.274 | 0.412 | |
| 18 | −0.023457179 | 2.0 | 1 | 21 | 1888 | 1.056 | 0.944 | |