Table 1.
Spectroscopic data for the new compounds (between 1 × 10–6 M and 4 × 10–5 M in DMF).
| Compound | Absorption λmax (nm) | Log ε (M–1 cm–1) | Emission λmax (nm) | Stokes shift (cm–1) | ФF (DMF)a |
|
| |||||
| 3a | 460 | 4.15 | 521 | 2545 | 0.69 |
| 4a | 460 | 4.11 | 522 | 2582 | 0.68 |
| 3b | 461 | 4.17 | 524 | 2608 | 0.83 |
| 3c | 461 | 4.25 | 525 | 2644 | 0.78 |
| 3d | 457 | 4.43 | 522 | 2687 | 0.73 |
| 4d | 459 | 4.46 | 521 | 2593 | 0.72 |
| 3e | 460 | 4.03 | 522 | 2547 | 0.71 |
| 3f | 456 | 4.33 | 523 | 2809 | 0.83 |
| 4f | 458 | 4.32 | 524 | 2750 | 0.66 |
aExcitation at 436 nm. N,N’-Dibenzyl-DPP was used as the fluorescence quantum yield reference: ΦF = 0.88, in chloroform [40].