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. 2024 Aug 8;15(35):14406–14414. doi: 10.1039/d4sc03518f

Second-order rate constants for the reaction of [OCP] with reference electrophile in acetonitrile at 20 °C.

Electrophile k 2 (M−1 s−1)
1a a
1b a
1c 2.52 × 109
1d 2.18 × 109
1e
1f 1.04 × 108
1g 9.67 × 107
1h 2.23 × 108
1i 1.08 × 108
1j 1.77 × 107
1k 1.74 × 104
1l 2.98 × 102
1m 2.17 × 102
1n 3.71 × 101
a

Very fast reaction.