Second-order rate constants for the reaction of [OCP−] with reference electrophile in acetonitrile at 20 °C.
| Electrophile | k 2 (M−1 s−1) |
|---|---|
| 1a | —a |
| 1b | —a |
| 1c | 2.52 × 109 |
| 1d | 2.18 × 109 |
| 1e | — |
| 1f | 1.04 × 108 |
| 1g | 9.67 × 107 |
| 1h | 2.23 × 108 |
| 1i | 1.08 × 108 |
| 1j | 1.77 × 107 |
| 1k | 1.74 × 104 |
| 1l | 2.98 × 102 |
| 1m | 2.17 × 102 |
| 1n | 3.71 × 101 |
Very fast reaction.