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. Author manuscript; available in PMC: 2024 Aug 19.
Published in final edited form as: Chem Rev. 2023 Jul 31;123(16):10381–10431. doi: 10.1021/acs.chemrev.3c00215

Scheme 60. (A) Distribution of Para and Meta Products in the Alkylation of Several Benzofurans by Artificial Iridium-Containing P450s;406 (B) Lactam Formation via Intramolecular Cyclization by Engineered Artificial Copper–Streptavidin Metalloenzymes with Major Products Displayed with the Corresponding Percent of the Product Pool407.

Scheme 60.