. 2024 Aug 6;128(32):6745–6756. doi: 10.1021/acs.jpca.4c03653

Table 5. Rate Coefficients (in Units of cm³ molecule^–1 s^–1) for the Gas-Phase Reaction of Ozone with Methyl-butenols and Their Alkene and Carbonyl Structural Homologues.

methyl-butenol	k_O3 × 10¹⁸^a	alkenes	k_O3 × 10¹⁸	k_MBO/k_alkene	carbonyls	k_O3 × 10¹⁸	k_MBO/k_Carbonyl
3-methyl-2-buten-1-ol	311	2-methyl-2-butene	403³⁸	0.77	3-methyl-2-butenal	1.82⁵⁴	171
3-methyl-3-buten-1-ol	7.29	2-methyl-1-butene	14.30⁵²	0.51
3-methyl-3-buten-2-ol	62.9	2-methyl-1-butene	14.30⁵²	4.40	3-methyl-3-buten-2-one	11.8⁵⁵	5.33
2-methyl-3-buten-1-ol	4.25	3-methyl-1-butene	7.30³⁷	0.58
2-methyl-3-buten-2-ol	9.55	3-methyl-1-butene	7.30³⁷	1.30

This work.

Table 5. Rate Coefficients (in Units of cm3 molecule–1 s–1) for the Gas-Phase Reaction of Ozone with Methyl-butenols and Their Alkene and Carbonyl Structural Homologues.