Table 1. Results of the Synthesis of l-Proline Based Copolypeptides in ACN/Water (1:1 v/v).
| copolypeptide | monomer ratios, 1H NMR | diff coeff, ×10–10 [m2·s–1]a | dhydr [nm] (PDI)b |
|---|---|---|---|
| PPI-(PLP20)8 | 20/0 | 14.7 | |
| PPI-(PLP20-b-PBLG10)8 | 21/9 | 2.44 | 60 (0.31)c |
| PPI-(PLP20-b-PBLG20)8 | 19/19 | 1.57 | 65 (0.29) |
| PPI-(PLP20-b-PBLG40)8 | 20/44 | 1.07 | gel |
| PPI-(PLP20-b-PZLL10)8 | 20/10 | 2.51 | 57 (0.18) |
| PPI-(PLP20-b-PZLL20)8 | 20/22 | 2.45 | 69 (0.23) |
| PPI-(PLP20-b-PZLL40)8 | 22/48 | 2.13 | gel |
Obtained from DOSY 1H NMR.
Hydrodynamic diameter by DLS.
Nanoparticles were nonspherical.