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The antipode (ent-3ha) was synthesized using (S)-MeO-BIPHEP (ent.-L6) (see the Supporting Information).
Alkene (500 mol %), (R)-MeO-BIPHEP (7.5 mol %), and [Ir(cod)2]BARF (7.5 mol %) were used.
(R)-SEGPHOS (L4) was used.
