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. 2024 Sep 11;14(38):28201–28209. doi: 10.1039/d4ra04871g

Dynamic matrix constructor f(a) and accumulated points constructor g(a) for not the same mechanisms.

Function law name g(a) f(a) = (1/k)(da/dt)
Ordinary reaction
Phase–interface reaction a 1
Primary reaction –ln(1 − a) 1 − a
Secondary reaction (1 − a)−1 (1 − a)2
Tertiary reaction (1 − a)−2 (1 − a)3
 
Stage boundary control reaction
Shrinking cylinder 1 − (1 − a)1/2 2(1 − a)1/2
Shrinkage sphere 1 − (1 − a)1/3 2(1 − a)2/3
 
Diffusion-controlled reaction
Power function law a 2 1/2a
The Valensi equation (1 − a)ln(1 − a) + a [−ln(1 − a)]−1
The Jander equation [1 − (1 − a)1/3]2 3/2(1 − a)2/3[1 − (1 − a)1/3]−1
The G–B equation (1 − 2a/3) − (1 − a)2/3 3/2[(1 − a)−1/3 − 1]−1