Table 1.
Fatty acid composition of the outer (sn-1,3) and inner (sn-2) triacylglycerol (TAG) positions of the coconut oil (CO) and hemp oil (HO) blends with different oil ratios without interesterification and after 2 or 6 h of interesterification.
| Fatty Acid | Oil Type | Composition [%] | Distribution [%] | |
|---|---|---|---|---|
| C12:0 | TAG | sn-1,3 | sn-2 | |
| CO25HO75 0 | 8.99 ± 0.21 d | 0.64 ± 1.12 f | 95.15 ± 8.40 a | |
| CO25HO75 2 | 9.26 ± 0.62 d | 4.88 ± 1.63 de | 65.15 ± 9.37 b | |
| CO25HO75 6 | 8.99 ± 0.61 d | 3.38 ± 1.07 ef | 75.13 ± 6.26 b | |
| CO50HO50 0 | 19.21 ± 1.28 c | 7.43 ± 2.14 d | 74.42 ± 5.72 b | |
| CO50HO50 2 | 20.31 ± 0.61 c | 12.94 ± 0.72 c | 57.54 ± 1.07 cd | |
| CO50HO50 6 | 18.97 ± 1.03 c | 11.69 ± 2.12 c | 59.06 ± 5.23 cd | |
| CO75HO25 0 | 28.56 ± 1.65 ab | 18.25 ± 2.39 b | 57.49 ± 3.13 cd | |
| CO75HO25 2 | 29.74 ± 1.23 a | 21.65 ± 0.68 b | 51.38 ± 3.55 d | |
| CO75HO25 6 | 26.61 ± 0.63 b | 25.93 ± 1.22 a | 35.05 ± 1.52 e | |
| C14:0 | CO25HO75 0 | 4.69 ± 0.02 d | 4.14 ± 0.20 e | 41.18 ± 2.70 a |
| CO25HO75 2 | 4.63 ± 0.09 d | 4.78 ± 0.06 e | 31.20 ± 0.50 bc | |
| CO25HO75 6 | 4.42 ± 0.20 d | 4.01 ± 0.3 e | 39.62 ± 2.90 a | |
| CO50HO50 0 | 9.03 ± 0.24 c | 9.78 ± 0.36 cd | 27.79 ± 0.76 cd | |
| CO50HO50 2 | 9.36 ± 0.30 c | 10.64 ± 0.48 c | 24.26 ± 0.98 e | |
| CO50HO50 6 | 9.32 ± 0.20 c | 9.23 ± 0.41 d | 34.01 ± 1.51b b | |
| CO75HO25 0 | 15.29 ± 0.57 a | 17.31 ± 0.81 a | 24.55 ± 0.70 de | |
| CO75HO25 2 | 13.90 ± 0.38 b | 16.09 ± 0.55 b | 22.86 ± 0.52 e | |
| CO75HO25 6 | 13.89 ± 0.47 b | 16.80 ± 0.66 ab | 19.34 ± 0.41 f | |
| C16:0 | CO25HO75 0 | 7.25 ± 0.007 e | 9.28 ± 0.10 d | 14.70 ± 1.02 d |
| CO25HO75 2 | 7.24 ± 0.35 e | 8.18 ± 0.98 d | 14.57 ± 0.97 d | |
| CO25HO75 6 | 7.005 ± 0.09 e | 8.54 ± 0.17 e | 18.68 ± 0.54 b | |
| CO50HO50 0 | 7.75 ± 0.12 d | 10.52 ± 0.17 c | 9.49 ± 0.08 e | |
| CO50HO50 2 | 7.75 ± 0.25 d | 10.04 ± 0.38 c | 13.62 ± 0.47 d | |
| CO50HO50 6 | 8.13 ± 0.07 d | 9.32 ± 0.16 d | 23.62 ± 0.60 a | |
| CO75HO25 0 | 10.01 ± 0.04 a | 12.50 ± 0.09 a | 16.75 ± 0.24 c | |
| CO75HO25 2 | 8.67 ± 0.04 c | 11.27 ± 0.08 b | 13.33 ± 1.07 d | |
| CO75HO25 6 | 9.31 ± 0.37 b | 11.34 ± 0.56 b | 18.77 ± 0.73 b | |
| C18:0 | CO25HO75 0 | 3.58 ± 0.14 cd | 4.69 ± 0.18 bcde | 12.56 ± 0.03 c |
| CO25HO75 2 | 3.58 ± 0.13 cd | 4.63 ± 0.23 bcde | 13.78 ± 1.04 bc | |
| CO25HO75 6 | 3.50 ± 0.04 cd | 4.43 ± 0.09 cd | 15.69 ± 0.62 b | |
| CO50HO50 0 | 3.67 ± 0.13 cd | 5.08 ± 0.21 bc | 7.76 ± 0.47 d | |
| CO50HO50 2 | 3.30 ± 0.02 d | 4.24 ± 0.04 d | 14.24 ± 0.12 bc | |
| CO50HO50 6 | 3.75 ± 0.14 bc | 4.47 ± 0.27 bcd | 20.59 ± 1.76 a | |
| CO75HO25 0 | 4.59 ± 0.37 a | 5.94 ± 0.53 a | 13.74 ± 0.71 bc | |
| CO75HO25 2 | 3.91 ± 0.19 bc | 5.13 ± 0.14 b | 12.40 ± 1.90 c | |
| CO75HO25 6 | 4.15 ± 0.27 b | 5.00 ± 0.43 bcd | 19.73 ± 1.73 a | |
| C18:1 n-9 | CO25HO75 0 | 12.20 ± 0.22 a | 12.49 ± 0.09 a | 31.70 ± 0.74 bc |
| CO25HO75 2 | 12.17 ± 0.22 a | 11.97 ± 0.47 a | 34.40 ± 1.39 ab | |
| CO25HO75 6 | 12.06 ± 0.12 a | 12.32 ± 0.21 ab | 31.85 ± 0.47 bc | |
| CO50HO50 0 | 10.56 ± 0.27 bc | 11.18 ± 0.40 b | 29.44 ± 0.67 cd | |
| CO50HO50 2 | 10.00 ± 0.33 cd | 9.84 ± 0.54 c | 34.37 ± 1.43 ab | |
| CO50HO50 6 | 10.92 ± 0.25 b | 11.81 ± 0.52 ab | 27.92 ± 1.51 d | |
| CO75HO25 0 | 10.30 ± 0.57 bc | 11.92 ± 0.82 ab | 22.89 ± 1.04 e | |
| CO75HO25 2 | 9.32 ± 0.34 d | 9.29 ± 0.09 c | 33.47 ± 3.15 ab | |
| CO75HO25 6 | 9.84 ± 0.44 cd | 9.29 ± 0.73 c | 37.09 ± 2.16 a | |
| C18:2 n-6 | CO25HO75 0 | 42.05 ± 0.07 a | 44.43 ± 0.96 a | 31.70 ± 0.74 cd |
| CO25HO75 2 | 42.04 ± 0.09 a | 42.16 ± 0.30 a | 34.40 ± 1.39 c | |
| CO25HO75 6 | 42.68 ± 0.60 a | 43.66 ± 1.14 ab | 31.85 ± 0.47 c | |
| CO50HO50 0 | 30.88 ± 0.91 b | 33.73 ± 1.55 b | 29.44 ± 0.67 d | |
| CO50HO50 2 | 28.64 ± 1.38 c | 28.98 ± 2.20 c | 34.37 ± 1.43 c | |
| CO50HO50 6 | 30.91 ± 0.87 b | 34.24 ± 1.67 b | 27.92 ± 1.51 d | |
| CO75HO25 0 | 18.25 ± 1.07 e | 20.24 ± 1.47 d | 22.89 ± 1.04 d | |
| CO75HO25 2 | 18.28 ± 0.73 e | 16.96 ± 0.40 e | 33.47 ± 3.15 b | |
| CO75HO25 6 | 20.30 ± 0.74 d | 14.67 ± 1.27 e | 51.87 ± 2.40 a | |
| C18:3 n-3 | CO25HO75 0 | 12.66 ± 0.03 a | 12.66 ± 0.03 a | 26.00 ± 1.34 e |
| CO25HO75 2 | 12.42 ± 0.26 a | 12.20 ± 0.53 b | 34.53 ± 1.47 bc | |
| CO25HO75 6 | 12.57 ± 0.16 a | 13.66 ± 0.26 a | 27.54 ± 0.46 de | |
| CO50HO50 0 | 8.94 ± 0.46 b | 9.83 ± 0.78 c | 26.71 ± 2.03 de | |
| CO50HO50 2 | 8.11 ± 0.34 c | 7.07 ± 0.55 e | 41.92 ± 2.05 ab | |
| CO50HO50 6 | 8.77 ± 0.22 b | 8.68 ± 0.46 d | 34.04 ± 1.79 bc | |
| CO75HO25 0 | 4.81 ± 0.36 e | 5.14 ± 0.48 f | 28.81 ± 1.32 de | |
| CO75HO25 2 | 5.22 ± 0.24 de | 5.44 ± 0.09 f | 30.45 ± 1.98 cd | |
| CO75HO25 6 | 5.83 ± 0.24 d | 5.02 ± 0.42 f | 42.67 ± 2.45 a | |
Determined data are presented as mean values followed by the standard deviation (±SD). The different lowercase letters in columns (for each fatty acid separately) indicate significantly different values (p ≤ 0.05).